化工废水的预处理及新型内电解装置的研究-环境科学与工程、环境工程专业论文.docxVIP

摘 摘 要 本文以实验为基础，针对化工废水的特点，选用了无曝气情况下的内电解工艺对 试验用高浓度化工废水进行了预处理研究。通过对pH、固液比、停留时间、铁炭质 量比，以及反应温度的研究，得出在pH值在4---5之间、固液比为0．8 g／m1、停留 时间为60 rain、铁炭质量比为3：1时，对COD的去除率可以达到71．6％、对色度的 去除率可以达到87．5％，污水处理前后的B／C值从O．09提高到O．19，有利于后续的 生化处理。 其次，针对目前一些内电解反应装置存在的缺点，设计了一种结构简单、操作方 便的新型反应器。并通过用两种不同的化工废水对新型内电解装置进行了无曝气条件 下的应用研究，发现对两种废水的色度及COD的去除效果较好、有工程化应用的前 景，同时，在整个实验过程中，铁屑装填便利。并发现只要保证内电解装置中的液面 高于铁屑与炭颗粒液面，铁屑就没有出现结块现象。 最后，应用铁炭内电解法组合工艺并以H202／草酸铁络合物为光氧化剂，对高浓 度化工污水进行了光氧化降解试验研究。结果表明，在日光照射下H202／草酸铁络合 物能使污水中的有机物迅速光解，晴天光照15 min，pH值为4，草酸根浓度为O．8 mmol／L，亚铁离子浓度为O．8 mmol／L，H202浓度为25 ml／L，可使色度和COD的去 除率分别达到87．5％和93．8％，在与内电解联合处理污水时，可使色度及COD的去 除率分别达到99．3％和96．9％，B／C值达到0．3以上。 关键词：化工废水；内电解法；新型反应器；日光；草酸铁络合物；过氧化氢 AbstractThis Abstract This work basing on experiments regards the pretreatment for a kind of chemical industry wastewater．A study of pretreatment of chemical industry wastewater with hi．gll concentration contamination by non—aerate inner-electrolysis Was carried out．The optimum operation conditions ale as follows：pH is 4--5，the rate of the solid quality and the liquid bu墩is 0．8 g／ml，HRT is 60 minutes，the reactive temperature is room temperature，the ratio of the iron and the active carbon quality is 3：1，the removal rates of COD and chromaticity were 7 1．6％and 87．5％respectively,the BODs／COD ratio was improved from 0．09 to 0．1 9，and the method reached a good pretreatment effect． Second，to overcome the drawbacks of the inner-electrolysis reactors a new type reactor with simple construction and operation convenience Was designed．Its appliance resets Was studied by two kinds of chemical industry wastewater on non-aerate inner-electrolysis condition．The results indicate that the removal rates of COD and chromaticity Was good pretreatment effect and its appliance foreground was well．The iron Was loaded expediently,contemporary．The iron Was not agglomeration on the condition that the iron Was blow the level of wastewater． Finally,the photo oxidative degradation of chemical industry wastewater with high concentratio