基于团簇结构模型的高温近α-Ti合金成分规律探究及设计-材料物理与化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 基于团簇结构模型的高温近0 基于团簇结构模型的高温近0【-Ti合金的成分规律探究及设计 系列中，Hf元素的添加进一步提升了系列合金的抗氧化性能及耐蚀性能，其中 A1-(Til3．7Hfo．3)．(Alo．69Sno．1sTao．015Nbo．olsSio．1)合金在800℃抗氧化性能最强，氧化增重为 2．6 mg／em2，氧化层厚度仅为15 pm；Zro．15H而．15系列中Zr、Hf,Ta与Nb共同作用下合 金为双态组织，优异的综合力学性能和抗高温氧化能力。 关键词：近G-Ti合金；团簇加连接原子模型；合金设计；高温氧化 万方数据 大连理工大学硕士学位论文Study 大连理工大学硕士学位论文 Study on the composition rule and design of high-temperature near-仪Ti alloys via a cluster-based structural model Abstract High-temperature near一仅Titanium alloy iS one of the important structural materials in aircraft engine due to its comprehensive mechanics performance as well as good oxidation·and corrosion-resistance．In order to satisfy causative perfromance，multiple elements are added simultaneously into the base Ti，including HCP一仅stabilizer A1，BCC—D stabilizers Mo，Nb，Si， neutral stabilizers Zr，Sn and rare earth elements Y，Ce and Nd．The A1 equivalent method， d-electron theory，electron concentration criterion and BP nepal network were put forward to design high temperature Titanium alloys because of multi—element composition complexity and making sure structure stability of Titanium alloys．Near-仅Ti alloys are solid solutions，on the basis of local chemical short range，our group proposed a cluster-plus-glue—atom model for stable solid solutions to explore the rule of near-a Ti alloys composition．This model contains a cluster part and a glue atom part．where the clusters are nearest—neighbor polyhedrons、析t11 strong interactions and glue atoms are located in-between the clusters with weak interactions． The cluster formula Can be written as[Cluster](Glue atom)x(x is the number of glue atoms)． The present work investigated the composition rule ofthe typical near-a Titanium alloy Ti l 1 00 using a cluster-plus-glue-atom model for solid-solution alloys，and its cluster formula could be expressed as[A1-(Til3．7Zr0．3)](A10．69Sno．18M00．03Sio．12)，X21．Three new series of alloys by adding minor nf,Ta and Nb witll similar elements substitution in equal·mole mode were