基于喹啉母体的新型席夫碱类荧光传感器的合成及其性能研究-化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 内蒙古大学硕士学位论文 内蒙古大学硕士学位论文 的金属离子，而L2在乙醇溶剂中对A13+表现出了高的选择性和灵敏性，且在识 别离子过程中是基于ESIPT和PET两个机理的。 关键词：荧光传感器；8．羟基．2．甲基喹啉；A13+；Fe3+；PET；ESIPT 万方数据 内蒙古大学硕士学位论文1l 内蒙古大学硕士学位论文 1l匝SYNllⅢSIS AND PROPERTIES OF NOVEL SCHIFF BASE FLUOI之ESCENT SENSORS BASED ON QUlNOLINE AB STRACT Fluorescent sensors have been proved to be useful tools for sensing metal cations，anions and amino acids in vivo and vitro．The more and more researchers have paid more attention to study the fluorescent sensors because of their high selectivity,good sensitivity,easy operational use and fast response times with respect to traditional analytical methods．Schiff base is an ideal fluorescent sensoL Not only Schiff base is easily to be synthesized，but also it can provide nitrogen which coordinates with metal ions．So recently,much attention has been paid to the synthesis and study of Schiff base fluorescent sensors by some researchers． In this paper,four novel Schiff base L，LI，L2 and L3 have been synthesized by modifying the 2 and 8 positions of 8-hydroxy·-2--methyl quinoline by different substituent groups．They are as follows： First，according to the Hard-Soft—Acid-Base theory,the 8-hydroxy-2·methyl quinoline’S nitrogen and oxygen Can provide a hard—base environment for hard—acid A13+．After being modified the 8-hydroxy一2 methyl quinoline，the sensor L has a high selectivity and sensitivity for detecting A13+in ethanol solvents．The binding ratio 万方数据 内蒙古大学硕士学位论文between 内蒙古大学硕士学位论文 between A13+and L was 1：2，which was determined by the Job’S plot．The binding mechanism was studied to be based on PET mechanism． Second，the sensor L l Was synthesized by reacting 8-hydroxy-2-quinoline formaldehyde with hydrazide．When other metal ions and Fe3+coexist in DMSO solvents，the sensor L 1 showed a high selectivity and anti—interference ability for recognizing Fe3+，and the remarkly fluorescence quenching can be achieved． Third，the sensor L2 was synthesized by reacting 8-hydroxy-2-quinoline formaldehyde with 4-ami