典型不锈钢耐局部腐蚀性能改善的研究-物理电子学专业论文.pdf.docxVIP

复 旦 复 旦 人 学 硕 丨：学 位 论 文 A B S T R A C T S ta in less stee ls refer to th e iro n -b ased allo y s w h ich h av e ch ro m ium co ntent n o less th an 12 w t.% , an d ex h ib it ex ce llen t o x id atio n re sistan ce in a ir. S tain less stee ls co u ld b e c lassified to 5 serie s.A m o n g th e se serie s,th e au ste n itic sta in less stee ls are th e m o st w idely used steels and th e dup lex sta in less steels are irrep laceab le in som e area，so th ere is n o do ub t th at th e research es to th ese tw o series o f stee ls are v ery h ot. D uring the serv ice p rocess of stain less steels, vario us k in ds of localized corrosio n s w h ich ind uced by p ittin g an d intergran u lar co rro sion co u ld cause h uge dam ages. S o m e techn o lo g ies h av e b een introd uced to the pro d uce an d serv ice processes to enh an ce th e resistance to lo calized corrosio n s, such as ad d itio n o f allo y elem ents or cho o se appro priate h eat-treatm en t con d ition s. B ased on th e sa id b ackgro u nd ,the resistan ce to lo calized corro sion o f several typ ical stain less steels w h ich had ex p erien ced such techn o log ies w as ev alu ated by electro chem istry m etho d s and th e m icro structures w ere characterized b y m icro scopy tech niq ues in th ese pap er,th e detailed research contents are d escribed as the fo llow in g asp ects: (1)W ith th e testing of p itting potential (E b) using potentiod y nam ic po larization cu rve and the ratio of reactivation(及a) u sing do ub le loo p electrochem ical poten tiody nam ic reactiv atio n(D L -E P R ), th e effect o f the ad ditio n of N itro gen(N ) and N io b ium (N b ) o n th e p ittin g co rro sion an d interg ran u lar corro sio n beh av io r o f 3 04 au sten itic sta in less steels w as in v estig ated . T h e resu lts show ed that, th e sp ecim en s w ith N a n d N b a d d itio n e x h ib ite d b e tte r re s ista n c e to lo c a liz e d c o rro s io n th a n th o se