聚氧化乙烯-聚己内酯嵌段共聚合成及其在取向pe基底上附生结晶-材料科学与工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 晶结晶形貌的研究，解释了嵌段共聚物环带球晶生长过程。 晶结晶形貌的研究，解释了嵌段共聚物环带球晶生长过程。 3．附生结晶体系的实验中，利用熔融拉伸法制备了高度取向PE超薄 膜；偏光样品旋转消光现象说明聚合物发生了取向结晶。利用三明治夹心结 构解决了聚合物的团聚问题，通过揭膜法对嵌段共聚物在取向PE基底上片 晶取向结构进行了表征。取向PE基底对于嵌段共聚物中PEO链段的结晶形 态影响很小，但PEO链段的加入不利于嵌段共聚物中PCL链段在取向PE 上的附生结晶。 关键词：聚氧化乙烯，聚(￡一己内酯)，嵌段共聚物，取向基底，附生结晶 万方数据 一 一 垒里墨!垦垒￡! SYNTHESIS AND THE EPITAXIAL BEHAVIoR oN oIUENTED PoLYETHYLENE SUBSTRATE oF PE0．b—PCL ABSTRACT Poly(e—caprolactone)has been widely used in drug carrier material and surgery short—term implants．As we know,Poly(e—caprolactone)is hydrophobic， which restrains its applications．with poly(ethylene oxide)attached to poly(e—caprolactone)can improve the hydrophilic defection，which is hydrophi lic． the synthesis and the crystalline behavior study of poly(ethylene oxide)··b-poly(e—·caprolactone) copolymers were rapidly promoted by biocompatibility,amphiphilicity,self-assembly,permeability,and controllable biodegradability．Crystallization behavior has important implications for the final physical properties，mechanical properties，biodegradable properties and drug release mechanism of biological materials．Hetero—epitaxy of polymers has been extensively studied for it provides a useful way to control the crystall ine structure of a wide variety of semi—crystalline polymeric materials．In hetero—epitaxy system，the effect of the substrate on the epitaxial substances results in the strict orientation relationship between the two，which can produce unusually morphological structure．Due to the strong physical binding of epitaxial interface has a great influence on the mechanical properties of the material，which causes widespread concerns． 1．A series of different weight fraction ratio of PEO—b—PCL block copolymers were synthesized by living radical polymerization method。The crystallinity of fixed molecular weight PEO segment would change with different weight ratios．The PEO segment does not crystalline when the weight III 万方数据 北京化工大学硕士论文ratio 北京化工大学硕士论文 ratio of PEO is less than 1 6％．The sphe