锂离子电池铁基电极材料的制备与电化学性能研究-应用化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 山东大学硕士学位论文第三章四方双锥状 山东大学硕士学位论文 第三章四方双锥状Fe5004)4(olI)3．2H20的可控制备、结构表征及=兵电化学性 能研究 47 3．1引言 ．47 3．2制备过程 ．48 3．2．1实验药品与仪器 ．．j 48 3．2．2实验方法 49 3．3结果与讨论 ．5l 3．3．1四方双锥状Fes(P04)4(OH)3-2H20的制备与结构表征 ．51 3．3．2四方双锥状Fe5(P04)4(OH)3·2H20的形成过程 ．53 3．3．3四方双锥状Fes(P04)4(OH)3·2H20的电化学性能 ．56 3．4本章小结 ．59 参考文献 60 致谢 “ 攻读硕士学位期间发表的学术论文及成果目录 ．65 万方数据 山东大学硕士学位论文CoNTENTS 山东大学硕士学位论文 CoNTENTS Abstract in Chinese ． ．．I Abatract in English ． ．． III List of Symbols V Chapter 1．Introduction ．．． ．． 1 1．1 Background．． ． ． ．． ． ． ． ． ．． ． ． ． ． ． ． ．1 1．2 Overview of Lithium Ion Batteries ． ．． ． ． ．． ．． ． ．．．2 1．2．1 Development of Lithium Ion Batteries ．．2 1．2．2 Composition and Principle of Lithium Ion Batteries ．．3 1．3 Cathode Materials 4 1．3．1 Layed Cathode Materials ．．5 1．3．2 Spinel Cathode Materials 一6 1．3．3 Polyanion Cathode Materials ．．7 1．4 LiFeP04 Cathode Material ．9 1．4．1 Crystal Structure and Lithium—Ion Transport Mechanism of LiFeP04 ．．1() 1．4．2 Preparation Methods ofLiFeP04 13 1．4．3 Iron Phosphate and Iron Hydroxide Phosphate Cathode Material．1 5 1．5 Signficants ofthe Dissertation 16 References ．?L’I Chapter 2．Etching Preparation of(010)-Defective LiFeP04 Platelets to Visualize the One-Dimensional Migration of Li十Ions 28 2．1 Introduction ．．28 2．2 Experimental Section ．．29 2．2．1 Reagents and Apparatus ．．29 2．2．2 Methods 3 l 2．3 Results and Discussion ．．32 2．3．1 Etching Preparations of(010)-Defective LiFeP04 Platelets ．32 2．3．2 Electrochemical Characterization of(010)-Defective LiFeP04 Platelets ．．36 2．4 Conclusions ．42 万方数据 山东大学硕士学位论文References 山东大学硕士学位论文 References ． ． ． ． ． ． ． ． ． ． ． ．． ． ． ． 43 Chapter 3．Preparation，Structural Characterization and Electrochemical Characterization of Tetragonal Bipyramid Fes(P04)4(OI-I)3．2H20． ．47 ：；．1 Introduction ． ． ． ． ． ． ． ． ．． ． ． ． ．47 3．2 Experimental Section． ． ． ． ． ． ． ．48 3．2．1 Reagents and Apparatus ．48 ：；．2．2 Methods． ． ． ． ． ． ． ． ． ． ．．49 ：；．3 Results and Discussion． ． ． ． ． ． ． ． ． ． ． ． ．．5 1 3．3．