双极膜电解提溴吸收完成液制备HBr和NaOH-华东理工大学学报.PDF

DOI:10.14135/ki. 1006-3080.20180306001 双极膜电解提溴吸收完成液制备HBr 和NaOH 乔 婧，孙玉柱，宋兴福，于建国 (华东理工大学国家盐湖资源综合利用工程技术研究中心，上海 200237) 摘要：采用双极膜电渗析（BMED）技术，对以提溴吸收完成液为原料，电解制备 NaOH 和HBr 进行了研究。系统研究了电流强度、原料液的初始质量浓度以及酸碱的初 始浓度等参数对实验的影响，还考察了在盐室的NaBr 溶液中加酸的实验效果，用来模 拟以甲酸钠溶液为提溴过程中的吸收液所生成的吸收完成液。结果表明：适当的提高膜 堆的直流电强度有利于产酸产碱，但是与低的电流强度相比，电流效率更低，能耗更高， 综合考虑，实验采用的电流强度为2.5-3.0 A 。当原料液NaBr 的初始质量浓度为40-50 g/L 以及酸碱初始浓度为0.1-0.2 mol/L 时，电流效率较高，能耗较低。酸碱初始浓度越高， 电流效率和能耗的变化都随之而下降。在NaBr 原料液中加酸会抑制碱的产生，相反的， 产酸量则会大大提高。 关键词：双极膜；电渗析；NaBr ；酸碱 中图分类号：TQ028.3 文献标志码：A Preparation of HBr and NaOH by Bipolar Membrane Electrolysis from Absorbed Complete Fluid of Bromine Extraction QIAO Jing, SUN Yu-zhu, SONG Xing -fu , YU Jian-guo (National Engineering Research Center for Integrated Utilization of Salk Lake Resource, East China University of Science and Technology, Shanghai 200237, China) Abstract: Bromine is an important basic chemical raw materials. The traditional process of bromine extraction needs to absorb the free bromine monomer into the absorbed complete solution. Then through distillation, condensation, washing and other steps, the refine bromine can be achieved. But the steps are tedious, and a large number of stream and condensated water is needed. Also, the energy consumption of this method is great, and the equipment scale of occupying is large. Therefore this paper provides a new idea of the short process and high added value utilization in the process of bromine extraction, and comes up with a new way to produce HBr. In this paper, the bipolar membrane electrolysis(BMED) technology was used to prepare NaOH and HBr with NaBr as the raw material. The effects of the current intensity, the initial concentrat