嵌入型纳米零价铁的稳定性及微生物毒性机制研究-环境科学专业论文.pdf.docxVIP

AbstractAbstract Abstract Abstract Nano zero—valent iron(nZVI)，as an inexpensive and environmentally friendly reducing agent，has been widely used for polluted soil，groundwater and wastewater remediation with both in situ or ex situ applications．At present，studies have demonstrated that nZVl was effective for degrading a range of common environmental contaminants．However,one of the major issues associated with nZVl was that it was easy to agglomerate into large particles due to intrinsic magnetic interaction and van der waals forces，limiting the practical application of nZVI．In addressing this issue，it is necessary tO modify nZVl with several types of coatings or to load nZVI onto an appropriate support tO enhance its stabi lity and reactivity．Despite the widespread and enormous potential use of nZVI for environment remediation，there are growing concerns about the biological harm that may be caused by the nZVI materials because these particles easily exposed to human，animals and microorganisms．Therefore，it is necessary to assess and address the toxic effects of these nZVI materials on microbial activity． In this paper,nZVI／partly—graphitized carbon(nZVI／PGC)composites were prepared using a carbothermal synthesis method，and the synthesized nZVI particles were distributed uniformly on the graphitized carbon skeleton，which has the advantage in surface area，stabi lity and reactivity．The composite materials were characterized using X-ray diffraction(XRD)，nitrogen adsorption／desorption， thermogravimetry(TG)，Scanning electron microscopy(sem)，and to investigate the removal capacity of pollutants by degradating RhB．At the same time，nZVI and Si02 coated nZVI(nZVI@Si02)were prepared by a solution reduction method，and to investigate the toxic effects of the three kinds of nZVI particles on E coli cells．The results show that： 万方数据 黑龙江大学硕士学位论文(1)The 黑龙江大学硕士学位论文 (1)The most stable and active Fe／Fe304／PGC composite exhibits high removal efficiency of rhodamin B(RhB)，and the removal