纳米钨酸盐的湿化学制备工艺及性能探索研究-材料科学与工程专业论文.docxVIP

优秀毕业论文 精品参考文献资料 拟太阳光照射时，W03 拟太阳光照射时，W03和ZnW04质量比为5 wt％的W03／ZnW04．HT样品对 亚甲基蓝的降解率为95％。 关键词：钨酸盐材料，光催化性能，电化学一．14=土1--台日匕e_．,，拓扑转变 Ⅱ 万方数据 Wet Wet Chemical Preparation Technology and Properties Exploration Resarch of Tungstates Nanomaterials ABSTRACT In the recent years，tungstates have been recognized嬲advanced energy storage system in superconductors，solid fuel cells，humidity sensors， electrochromic devices，gaS sensor and solar filter，etc．due to their unusual physical and chemical properties． In this communication，we synthesized the potaSsium paratungstate (K10W12041‘l 1H20)，zinc tungstate(ZnW04)，tungsten trioxide／zinc tungstate (W03／ZnW04)phaSe by wet chemistry methods．Moreover，the influences of preparation conditions on the photocatalytic and electrochemical properties of the products were studied and the results嬲follows： (1)The KloWl2041‘1 1I-／20 nanorods were prepared by a hydrothermal method using W03 and KOH嬲start materials under the conditions of W依=1／40，pH=6，T=180。C，t=-12 h and no template agent．In addition the nanorods diameter WaS about 50．1 50nm and the length WaS about 200．800 nm． We explored the photocatalytic performance of KloWl204l。1 1 H20 nanorods，the KloWl2041’11H20 nanorods displayed the degradation efficiency of about 75％ for MB after UV-light irradiation for 50 rain．Moreover，the electrochemical performance of K,0W12041‘1 1 H20 WaS also investigated and the results indicated that the硒-prepared sample exhibited the high initial discharge capacity of 320 mAh g-1，the simple showed good cycle stability嬲lithium ion battery eletrode and the discharge capacity gradually stabilized at 1 1 0mAh g～after five cycles． (2)The ZnW04 nanoparticles were prepared by hydrothermal method using K10W1204l‘1 1 H20 nanorods and Zn(COOCH3)2·21420硒start materials．The ZnW04 nanoparticles were obtained at the conditions of 1 80 oC and W／K-1／40， and the nanoparticles product within the diameter of 20．50 nm．In addition．the ZnW04 nanoparticles displayed the degradation effi