混合焓对大块非晶合金玻璃转变温度的影响.pdf

A parameter influencing the glass transition temperature of bulk metallic glass * Xuelian Li, Xiufang BianTPF FPT , Lina Hu, Yuqin Wu, Junyan Zhang Key Laboratory of Liquid Structure and Heredity of Materials, Ministry of Education, Shandong University, Jinan 250061, China Abstract The authors propose that there is a linear relationship between the glass transition chem temperature (TBgB) and δ (defined as the absolute value of the mixing enthalpy (ΔHP P)). Larger δ results in the higher TB B . Underlying the investigation is that the change of TB results from theB g g change of excess entropy (SBexB) during thermal excitation. And the δ corresponds the part of the SBex atB TBg (B SBex (B TBgB)). A simple method is established for quickly identifying the tendency of TBg B of bulk glass-forming systems. Keywords : glass transition temperature; bulk metallic glasses; the mixing enthalpy; potential energy landscape 1. Introduction Soon after the introduction of the concept-“topographic view of the Potential Energy Landscape (PEL) [1],” and Angell’s classification of strong and fragile liquids [2], condensed matter physics has attracted more and more attention. Glass transition temperature (TB