光学活性聚炔核壳复合微球的制备及其应用研究材料科学与工程专业论文.docxVIP

北泵化工大掌坝士字位论文关应用实践。 北泵化工大掌坝士字位论文 关应用实践。 本论文的主要研究内容如下：l、以Triton X．100作为乳液聚合 乳化剂，对炔基化的Fe304进行乳化，加入取代炔单体后进行聚合， 从而制备得到粒径在1 gm左右，尺寸大小均一的Fe304@取代聚炔核 壳复合微球。通过扫描电镜和透射电镜的表征，观察了核壳微球的整 体结构和表面形态。通过圆二色谱和紫外测试表征了核壳微球的光学 性能。通过磁滞回线的测试表征了核壳微球的磁性能。通过核壳微球 对苏氨酸过饱和溶液两次诱导结晶过程，得到的苏氨酸晶体的e．e．值 (对映体过量)达到90％左右。并且通过在诱导结晶过程中跟踪取样 测定SEM和旋光，来揭示诱导结晶过程中晶体形态和e．e．值的变化。 2、首先通过含有邻苯二酚侧基基团的聚炔单体3与单体l进行 共聚反应制备得到含有邻苯二酚基团的螺旋取代聚炔，通过金纳米粒 子与邻苯二酚基团络合作用生成聚炔@金纳米粒子核壳复合微球。通 过透射电镜观察，得到粒径在500 nm左右的核壳微球，粒径大小基 本均一。圆二色谱和紫外的测试表征合成得到的核壳微球具有良好的 光学活性。 关键词：手性，磁性，核壳结构，乳液聚合，诱导结晶，螺旋取代聚 炔 万方数据 ABSTRACTPREPA ABSTRACT PREPA R ATIoN AND APPLICATIoN oF oPTICALIjY ACTIVE CoRE．SHELL CoMPoSITE MICRoSPHERES CoNSTRUCTED BY HELICAL SUBSTITUTED POLyACETYLENE ABSTRACT Synthetic helical polymers have received a great deal of attention owing to their distinctive helical structures and the corresponding properties that cannot be found in usual polymers．Helical polymers have visually elegant structures and possess fascinating optical activity,chiral amplification effect，etc．Because a conjugated structure of alternating single and double bonds exists in the main chain of polyacetylene，it exhibits special properties， such as electroconductivity and paramagnetism．Polyacetylene has also encountered some restrictions in the application；for instances，it is hard to dissolve，manufacture and its stability is relatively low．To overcome these drawbacks，scientists synthesized substituted polyacet’7lene nanoparticles．RecentlN researchers synthesized substituted polyacetylenes microspheres from nanometers to micrometers by emulsion polymerization，precipitation polymerization and suspension polymerization methods．The substituted polyacetylene microspheres were successfully applied to chiral recognition． Core／shell structured composite particles，which excellently combine 万方数据 万方数据 万方数据 北京化工大学硕士学位论又the 北京化工大学硕士学位论又 the advantages of the core and the shell components，are gathering rapidy increasing interest，because their composition，morphology,and properti