双亲性聚合物构象的光谱学方法研究材料工程专业论文.docxVIP

摘要中偶氮生色团顺反异构动态平衡的速率有显著的影响，且在光照过程中形成了面 摘要 中偶氮生色团顺反异构动态平衡的速率有显著的影响，且在光照过程中形成了面 对面平行堆积的H一聚集体。 关键词：瑞利光散射光谱法；本征荧光光谱法；双亲性聚合物；分子构象 万方数据 AbstractAbstract Abstract Abstract Amphiphilic polymers possess excellent molecular structural designing and significant functional applications due to their hydrophilic and hydrophobic segments Molecular conformation investigation is hot topic of amphiphilic polymers at the molecular level．Recently,the conformational change and its influence factors have attracted more and more attention．Several kinds of technologies have been used for conformational research，including atomic resolution transmission electron microscopic(AS—TEM)，cryogenic scanning electron microscopy(Cryo—SEM)，pulsed electron-electron double resonance(PELDOR)，high resolution NMR(HT-NMR)and dynamic light scattering(DLS)et a1．Althou曲having some shortages，the methods above being used widely and their values are being fully recognized Despite all these above，it’s of great significance to develop some characterization methods that have the merits of easy operation，hi．gh sensitivity and low destruction Spectroscopic methods based on fluorescence spectrophotometer can be the that match well．Considering the properties of polymers，two different spectroscopic methods including rayleigh light scattering(RLS)and intrinsic fluorescence spectrometry(Ⅲ)，were used to investigate the conformational change of two different kinds of amphiphilic polymers at different conditions．The main contents and results were concluded as follows 1．Conformational changes of amphiphilic Pluronic F 1 08 aqueous solution at different temperature concentration conditions were studied by RLS．Research results showed that three conformational change stages including molecule transition area and micelle area appeared during the temperature rising process of Pluronic F 1 08 aqueous solution．CMT and CMC were also measured by RLS，which were quite consistent with the results acquired by DLS．Meantime，thermodynam