单螺杆挤出机高温裂解制备高分子蜡的研究机械工程专业论文.docxVIP

北京化工大学硕士学位论文l 北京化工大学硕士学位论文 l x lO—mlTl、热失重率低于5％。 关键词：聚乙烯蜡，热裂解，单螺杆挤出机，动力学参数 万方数据 ABSTRACTRESEARCH ABSTRACT RESEARCH oN MANUFACTURING MACRoMoLECULE Ⅵ(AX BY PYROLYSIS 0F PE AT HIGH TEMPERATURE IN SINGLE．SCREW EXTRUDER REACToR ABSTRACT Polyethylene wax(PEW) also known as macromolecule wax，an important additive was usually used in plastics，dyes，paints and many other industries．In recent years，its demand is increasing，In this paper，the cracking reactor is single—screw extrudeg and polyethylene was selected as pyrolysis feedstock．The effects of different pyrolysis process on properties of polyethylene wax were studied．Details are as follows： 1．Considering the existing single—screw extruder,a connection pipe with certain length was designed to extend the pyrolysis time of polyethylene。The hot liquid polyethylene wax was extruded into the self-designed cooling tank by extruder in order to be cooled and stored until it was taken out．So the experimental device platform Was set up with regard to continue producing wax by single—screw extruder at high temperature． 2．Based on the pyrolysis mechanism of polyethylene，analyzing the performance parameter of polyethylene Wax which was obtained at various process conditions，kinetic parameters of HDPE pyrolysis can be determined ⅡI 万方数据 北京化工大学硕士学位论文in 北京化工大学硕士学位论文 in the experimental device．Accordingly,the kinetic model of high—density polyethylene(HDPE)pyrolysis in the experimental device was established． Therefore，the molecular weight of polyethylene wax，produced by HDPE cracking at different process conditions，can be predicted via using above model，and has verified by experimental means． 3．This article focuses on the effects of pyrolysis temperature and screw speed on the properties of polyethylene waxes which were obtained by low density polyethylene(LDPE)and HDPE pyrolysis，the results realized that the product manufactured by HDPE pyrolysis has narrower molecular weight distribution and better thermal stability than which obtained