掺杂型黑色二氧化钛的制备及其光催化性能研究环境科学专业论文.docxVIP

AbstractAbstract Abstract Abstract Titanium dioxide(Ti02)，as the most widely used oxide semiconductor，has attracted considerable interest owing to its various applications in solar-driven hydrogen production，photocatalytic decomposition of pollutants，solar cells and SO forth，although the wide-band-gap material(3．2 eV)captures about 5％of solar energy．Many investigations have been attempted to enhance visible—light absorption by band structure engineering(e．g．element doping and oxygen deciency)．Nevertheless，the visible-light power harvest remains insufficient due to little effective light absorption and many carrier-recombination centers．Ve巧recently，the hydrogenation of black titania can boost its visible and infrared light absorption and ultraviolet(UV)light photocatalytic activity，In the reports，black Ti02 shows a great photocatalytic performance．This paper adopted the sol—gel synchronous synthesis method combined with an in—situ solid-state chemical reduction approach，followed by the mild calcinations(350℃)in argon atmosphere．To prepared the black N—Ti02；Ni-Ti02；N—Ni—Ti02 and Ti02 photocatalyst， studied photocatalytic mechanism and doping mechanism of doped modification Ti02 catalyst degradating methyl orange and Rhodamine B in visible light． The prepared samples were characterized by X-ray photoelectron spectroscopy (XPS)，Fourier transformation infrared spectroscopy(FT-IR)，transmission electron microscopy(TEM)，X—ray diffraction(XRD)，specific surfacte area analyses(BET)， Raman，UV-visible diffuse reflectance spectroscopy(UV-vis DRS)and EPR． It was showed that the doping amount of urea element and calcining temperature have influence on the performance of catalyst．The experimental results proved that the band gap of black N-Ti02 about 2．05 eV which have an excellent visible light absorption performance．When nitrogen doping amount reached O．1 mol and calcination ．III． 万方数据 黑龙江大学硕士学位论文temperature 黑龙江大学硕士学位论文 temperature was 450。C，the prepared catalyst have the best ph