水系二次电池mno2正极材料的制备及性能研究化学专业论文.docxVIP

北京化工大学硕士学位论文测试，出现了两个还原峰和一个氧化峰，说明zn2+的脱嵌是两步反应。对 北京化工大学硕士学位论文 测试，出现了两个还原峰和一个氧化峰，说明zn2+的脱嵌是两步反应。对 恒流充放电数据分析，发现只有当电解液中同时含有Zn2+和Mn2+时， Mn02才不会出现比容量衰减的现象，电解液中的Mn2+能够抑制Mn02的 结构变化，防止出现颗粒团聚和结构塌陷，增加Zn2+的嵌入的容量。 3、将Mn02电极在1 M Li2S04+2M ZnS04+O．05M MnS04电解液中不 同电位范围进行电化学测试，从循环伏安测试数据可以看出，只有当在合 适的电位范围进行测试才会出现明显的氧化还原峰并且不会出现衰减，说 明电解液中的锰离子需要在一定的电位下才能进行氧化一还原电化学反 应，维持Mn02结构的稳定，保持Mn02电极高容量和长寿命的特性。 4、将碳纳米管代替乙炔黑作为导电剂，用不同掺入方式与Mn02复 合电极进行电化学测试，结果表明，以溶液搅拌方式掺入碳纳米管，可保 证碳纳米管均匀分散于Mn02中，从而使电极表现出更佳的电化学性能， 相比较乙炔黑，放电比容量有了显著的提高。 关键词：水系二次电池，储能，Mn02正极，锌锰离子协同作用，电解液， 导电剂 万方数据 ABSTRA(了THE ABSTRA(了 THE PREPERATION AND RESEARCH OF Mn02 CATHODE FOR AQUEOUS RECHARGEABLE BATTERIES ABSTRACT With the progress of modem science and technology development， more and more eqmpmem need to rely on the power operation i．n civil and industrial production．In order to meet the modem electronics industry demand for electrical energy storage devices，it is imperative to develop hi曲capacity and long life battery．We got Mn02 nanomaterials by different synthetic methods．We carried out on the material structure and morphology characterization by X—ray diffraction(XRD)and scanning electron microscope (SEM)，and the electrochemical performance was measured by cyclic voltammetry(cv)，impedance and constant current charge and discharge．The results are as follow： 1、Different crystal structure Mn02 was synthesized by controlling the pH and reaction time．The electrochemical performance of Mn02 was tested by constant current charge-discharge and cyclic voltammograms．The 0【-Mn02，amorphous Mn02 and￡-Mn02 have the similar elecreochemical 万方数据 万方数据 万方数据 北京化工大学硕士学位论文performance 北京化工大学硕士学位论文 performance which was got from the structure and motphology analyze．With the Zn2+embedded in and out of the Mn02，the structure of Mn02 was changed． 2、The electrochemical performance of Mn02 was tested in the electrolytes of 1 M Li2S04，2M ZnS04，1 M Li2S04+0．05M MnS04 and 1 M Li2S04+2M ZnS04+0．05M MnS04．The rectangular cyclic voltammograms curve is the acc