二聚酸生产副产物——单体酸深加工研究化学工艺专业论文.docxVIP

硕士学位论文 硕士学位论文 摘要 摘要 本文以南方某化工厂二聚酸生产副产物——单体酸为原料，研究 开发为生物柴油和铝材轧制油添加剂。 论文采用GC／MS技术剖析了单体酸的组成，结果表明，样品主要 含肉豆蔻酸(12．16％)、棕榈酸(8．51％)、十八稀酸(23．37％)以 及硬脂酸(32．72％)。理化分析表明，单体酸的碘值#J 80912／1 009、 酸值为1 80mgKOH／g、皂化值为192mgKOH／g、水分为0．05％。 在此基础上，论文研究以单体酸和甲醇为原料，对甲苯磺酸为催 化剂制备生物柴油。通过单因素和正交实验，确定最佳工艺条件为醇 酸摩尔比3：l、催化剂浓度6％、反应时间3h、反应温度60℃。制得 的生物柴油产品甲酯含量大于98％，其性能指标达到0撑柴油。 最后，以单体酸甲酯、单体酸与单体酸甲酯的复配剂作为铝材轧 制油油性添加剂。论文考察了添加剂与矿物基础油的相容性，通过复 配，开发出新型铝材轧制油配方：基础油95％四9％、抗氧剂0．08％、 油性剂1‰5％。针对轧制油的润滑性、减缩性、抗磨性、退火清洁 性、抗氧化性等性能，进行实验室和工业试验。结果表明，新型铝材 轧制油的粘度在1．9--2．1删胡s之间，表面张力在30．7～31．90mN／m之 间，退火污染等级在II级以内，油膜强度大于245N，摩擦系数小于 0．01，并且轧后产品表面粗糙度小于0．063“rn，说明新型铝材轧制油 完全能满足铝材轧制工业生产的要求。 关键词单体酸，酯化反应，对甲苯磺酸，生物柴油，轧制油添加剂 AB AB STRACT Monomer acid as raw material，which was the byproduct of dimer acid from one of chemical plantds in China,was used to produce biodiesel and rolling oil additives． First,the chemical constituents of fatty acid in monomer acid were determined bv GC／MS．Fifteen fatty acids were predominated：myristic acid(12．16％)，palmitic acid(8．51％)，stearic acid(32．72％)，and oleic acid(23．3 7％)．Meantime，the physicochemical properties of monomer acid were researched．The conclusion showed that iodine value was 80912／l OOg，acid value Was 1 80mgKOH／g，saponification value Was 1 92mgKOH／g，and water Was 0．05％． Second，carrying out monomer acid and methanol as raw materials to study the acid-catalyzed process technology of biodiesel．And， P．toluenesulfonic acid Was used to catalyze methyl esterification of monomer acid．At the sanle time，with the parameter esterification ratio、 single factor and orthogonal experiment,the hi曲est conversion Was achieved when the mole ratio of methanol to monomer acid Was 3：1 with addition of 6％p-toluenesulfonic acid and reacted at 60℃for 3h． Under these conditions。98．25％of methyl esterification product Was obtained．Its properties reached to that of 0开diesel oil． At last,synthetic ester and momomer acid were tested as oiliness additives．The compatibility between additives and base oil was study． The eff