光固化快速成型树脂的制备及其阻燃改性材料科学与工程专业论文.docxVIP

北京化工大学硕士学位论文环丁烷类活性稀释剂，并采用FT-IR和核磁一维氢谱(1H-NMR)表征了 北京化工大学硕士学位论文 环丁烷类活性稀释剂，并采用FT-IR和核磁一维氢谱(1H-NMR)表征了 结构。探究了原料投比、催化剂用量、反应温度和时间对其产率的影响， 确定了最佳反应条件。该产物加入混杂型光敏树脂配方中，提高了树脂的 固化速率、机械性能和玻璃化转变温度，起到了优化混杂型光固化树脂配 方的作用。 为改善光敏树脂的阻燃性能，制备了阻燃型光固化树脂复合材料。通 过比较多种绿色环保无卤阻燃剂，确定了二乙基次膦酸铝(ADP)为比较 适合应用于光固化体系的共混型阻燃剂。通过对凝胶率、粘度、透射深度 的测试，研究了ADP用量对树脂光固化性能的影响。使用扫描电镜(SEM)、 氧指数(LOI)、热重(TA)、水平燃烧试验以及锥型量热仪测试证明了 ADP改性的紫外光固化树脂复合材料的阻燃性能较纯光固化树脂有明显 的改善，并初步揭示了ADP气相、固相阻燃的机理，基本达到预期研究 的目标。 关键词：快速成型(三维打印)，紫外光固化树脂，混杂体系，氧杂环丁 烷，阻燃改性 万方数据 ABSTRACTPREPARATION ABSTRACT PREPARATION oF THE RESIN FoR STEREOLITHOGRAPHY AND MODIFICATIoN STUDY oF FLAME．RETARDING ABSTRACT Stereolithography(SLA)is characterized by low energy consumption，low cost and high molding precision，which is one of the most important Rapid Prototy7ping(RP)processes，promoting the great changes in the field of manufacturing．However,the research of photosensitive resin for SLA has started late in China．The monopoly of the resin manufacturers overseas．and the lack of series of domestic selected photosensitive resin lead to the restriction of the application of SLA in China．In this case，the development of the high—performance，low—cost resin would have great practical significance to the promotion of rapid prototyping in our country． Starting from hybrid system，a photosensitive resin used for stereolithography was prepared，consisted of bisphenol A type epoxy resin E44 as prepolymer, alicylic epoxy resin CY 1 79 and ethoxylated trimethylolpropane triacrylate SR454 as reactive diluents．By FT-IR and tests of gel content，it is determined that the photosensitive resin could polymerized efficiently when the content of radical initiator 1 84 was 2％，and the content of cationic initiator PAG202 was 3％．By leaming the effect of the hybrid ratio of resin on thethermostability,capability,mechanical properties，curing shrinkage， etc，the best hybrid ratio 1：O．75 was determined．The tensile strength of the cured resin could be up to 5 7．1 2MPa，flexural strength