催化氧化萃取集成燃油脱硫工艺研究应用化学专业论文.docxVIP

ABSTRACTAn ABSTRACT An efficient extraction．oxidation catalytic system for deep desulfurization of model fuel was explored．A Mo／1一A1203 was prepared by impregnation method and characterized by X—ray diffraction(XRD)，Temperature-programmed reduction(H2一TPR)and N2 physical adsorption isotherms．The result exhibited the characteristic of mesoporous structure and revealed that A12(MoOa)3 might be more preferred for sulfur oxidation．Acetonitrile， methanol，N，N．Dimethylformamide，N—Methylpyrrolidone and H20 were added to investigate influence of extracting agents for extraction—oxidation desulfurization， Employments of acetonitrile and methanol showed synergistic action and improvement of DBT removal．Nevertheless，the extraction process iS the main contribution to sulfur elimination using N，N·Dimethylformamide and N—Methylpyrrolidone as extractants．A detailed parametric study was performed varying n(H202)／n(S)molar ratio， v(oil)／v(acetonitrile)，temperature，molybdenum loading，catalyst amount and sulfur species， to investigate their effects 011 desulfurization．Under n(H202)／n(S)molar ratio of 2．3，0．20 g catalyst and v(oil)／v(acetonitrile)=3：1， benzothiophene，dibenzothiophene and 4,6一dimethyldibenzothiophene could be almost completely removed over 1 6 wt％ Moly—A1203 catalyst in 40 minutes at 60℃． A mechanism based on extraction—oxidation was proposed that sulfur compounds were transferred to extracting phase firstly and then oxidized to sulfones in the extracting phase． Extraction process Was demonstrated to be quick step compared、肮m the oxidation．The advantages of the extraction·oxidation catalytic system are that hilgh removal rate of sulfur could be achieved under low n(H202)／n(S)and the stability of the catalyst Was improved significantly in this case．The oxidation desulfurization reaction followed the first order kinetics． The oxidation of thiophene in model gasoline with heterogeneous Fenton—like system has been investigated to develop a novel oxidative desulfuri