冬季轮胎胎面用橡胶复合材料的设计制备与性能研究材料科学与工程专业论文.docxVIP

北京化工大学硕士学位论文擦面为沥青路面时，路面的平均构造深度(TD)对胶料的抗湿滑性能产 北京化工大学硕士学位论文 擦面为沥青路面时，路面的平均构造深度(TD)对胶料的抗湿滑性能产 生主要的影响，表面微观硬度对胶料抗湿滑性能无明显作用。在相同的填 料体积分数下，60phr白炭黑填充胶料具有较高的抗湿滑性能与抗冰滑性 能。 (3)研究了树脂用量与胶料动态性能的变化规律；探究了低分子量 树脂与环保芳烃油在胎面胶复合材料中的应用。结果表明：萜烯类树脂 T-100在橡胶中用量大于2phr时，会明显增加胶料损耗柔量曲线的峰高以 及峰宽。与填充环保芳烃油的胶料相比，C5石油树脂的加入在保持滚动 阻力不变的基础上提高了胶料的抗湿滑性能和抗冰滑性能。基于C5石油 树脂填充胶料的优异性能，研究了其与两种间戊二烯类树脂(TL．1000树 脂与TL．Lll00树脂)对胶料性能的影响。和未填充树脂胶料相比，三类 树,iI旨DH入到胶料中改善了胶料的流动性能，TL．Lll00树脂改善橡胶制品 的抗湿滑性能与抗冰滑性能的程度最高。 (4)设计制备了树脂与纳米氧化铝并用的冬季胎胎面胶复合材料，‘ 并对其性能进行研究。结果表明：与仅仅添加树脂的胶料相比，树脂与纳 米氧化铝并用后改善了橡胶的抗湿滑性能，胶料的抗冰滑性能变化不明 显。 关键词：冬季胎，抗湿滑性能，抗冰滑性能，微观硬度，纳米氧化铝，树 脂，损耗柔量 II 万方数据 ABSTRACTDESIGN，PREPARATION ABSTRACT DESIGN，PREPARATION AND PROPERTIES RESEARCH oF RUBBER CoMPoSITE MATERIALS FoR WINTER TIRE TREAD ABSTRACT Due to its benefit in improving vehicle handling performance in snow and ice weather,winter tire is widely used in cold places．Serving as the most important factor of measuring tire properties，ice traction is mainly determined by the composition of the tire tread materials．Since the design and preparation of tire tread materials are significant，this thesis emphasizes on three factors—rubber matrix，filler system，resin—to design and fabricate winter tire tread compounds．At the same time，the relative properties of the compounds are also being investigated to see their potential applications in tire industry． (1)This experiment studies the relationship between tire properties and rubber matrixs differing in various weight ratios of natural rubbeg butadiene rubber and emulsion polymerized styrene—butadiene rubber． The results showed that NRIBR／ESBR composites have better physical III 万方数据 万方数据 万方数据 北京化工大学硕士学位论文properties 北京化工大学硕士学位论文 properties and wet skid resistance．Meanwhile they exhibit higher loss compliance peaks and wider range peaks than NR／BR comp osites，which indicates better ice skid resistance． (2)This experiment studies microhardness of rubber surfaces with different fillers(carbon black，silica and Nano—alumina)and relationsh