多孔tizrnb的制备及其孔隙影响因素的研究材料学专业论文.docxVIP

中文摘要本文通过真空粉末烧结制备了多孔TiZrNb合金，采用图像分析法对其孔隙 中文摘要 本文通过真空粉末烧结制备了多孔TiZrNb合金，采用图像分析法对其孔隙 特征进行分析，从而研究了各因素对烧结制品孔隙的影响。并通过SEM、XRD、 弯曲测试等手段和方法对烧结制品的物相组成、显微组织、力学性能等进行了分 析。结果表明： 随着压制压力的增大，烧结产物孔隙率和平均孔径下降，孔的圆整度上升。 烧结时间越长，烧结产物孔隙率、平均孔径都越小，圆度越大。这种影响在5h 以前比较明显。烧结温度在1000。C至1300C范围内，对孔隙率的影响趋势是随 着温度的提高，孑L隙率逐渐减小；对孔径的影响是先增大后减小，1 100C是个转 折点。烧结温度对于孔隙圆度的影响是随着温度上升，圆度上升，在1200。C左 右，孔隙的圆度已经达到一个极值状态。造孔剂NH4HC03的添加能有效改变烧 结产物的孔隙率和孔径大小，在添加20％质量分数的NH4HC03后，烧结产物孔 隙率达到40％以上，大孔隙孔径在几百微米左右。随着造孔剂添加量的增加，孔 隙率和孔径都增大，圆度下降。 压制压力为120MPa、烧结温度为1200。C、烧结时间为5h时，TiZrNb合金 的孔隙率为44．04％，其显微组织为近p型多孔钛合金，杨氏模量为1 7．9GPa，抗 弯强度为264．5MPa，布氏硬度值为153HB。 关键词： 多孔TiZrNb合金图像分析孔隙特征13相 AB AB STRACT In this paper，powder metal lurgy technique was employed to prepare porous TiZrNb alloy．The pore characteristics were investigated by the image analysis technology,then the factors effecting the pore were studied．Optical microscope， Scanning electron microscope(SEM)and X—ray diffraction(XRD)were adopted tO analyze the microstructure，and morphology of the alloy．Bending and hardness test were employed tO evaluate the mechanical properties of the porous TiZrNb alloy．The results show as follows： The porosity and the diameter of the pores in the alloy were decreased，and the roundness of the pores became more perfect with the pressure increasing．The longer the sintering time，the smaller the porosity and the pore diameter,and the rounder the pores were．This effect was apparent when sintering time was less than 5 hours．When the sintering temperature increased between 1 000℃and 1 300℃，the porosity of porous alloy decreased．The diameter of pores became bigger as the increasing of sintering temperature until it reached 1 I 00C，after then the diameter of pores decreased．The pores of alloy sintered at 1 200(2 possessed the highest roundness．The effect of NH4HC03 the pore characteristics was sign i ficant．The porosity of the alloy prepared with 20％NH4HC03 was well above 40％，and the diameter of large pores of this alloy was more than 200“m．With the content of