大颗粒立方氮化硼单晶的合成工艺研究材料学专业论文.docxVIP

山东建筑大学硕士学位论文 山东建筑大学硕士学位论文 cBN单晶产量为99．6ct，转化率为33．2％，大颗粒单晶(30／50目)的产量占比为56．8％。 测得50／60目粒度cBN单晶的抗压强度值为48N，高出相应国家标准。合成出的cBN单 晶为琥珀色，透明度较高，部分尺寸为O．5mm左右，晶形为典型的八面体，晶面多为(1 11) 和(1 10)面，表面光滑，缺陷较少。该工艺为目前实验研究的最优工艺，适合于工业大 规模生产高品级、大颗粒的cBN单晶。 (5)采用Ca3N2．hBN体系+籽晶合成cBN单晶，添加4wt％的100／120目籽晶合成 cBN单晶的产量为67．1 ct，转化率为22．4％，大颗粒单晶(30／50目)的产量占比为14．4％。 测得50／60目粒度的cBN单晶的抗压强度值为45N，高出相应国家标准。合成的cBN单 晶为浅黄色，透明度较高，部分晶粒尺寸在0．5mm左右。晶形为截角八面体，晶面多为 (111)和(110)晶面，表面平整，有少许缺陷。但是与Li3N-hBN体系+籽晶相比，合 成cBN单晶的效果较差一些。 关键词：高温高压，大颗粒cBN单晶，功率平走．慢超压合成工艺，粒度 Ⅱ 万方数据 山东建筑大学硕士学位论文The 山东建筑大学硕士学位论文 The research of bulk particle cubic boron nitride single crystal synthesis process Su haitong(Materials Science) Directed by Xu Bin ABSTRACT With the high hardness，good thermal stability,good chemical inertness and high oxidation resistance，the cubic boron nitride(cBN)has been rapidly devdoped and applied since the first synthesis．As one of the most important applied materials in the 21th century，it is recognized to bring the new revolution for the grinding and cutting technology．At presem although our country has became a major production country,compared with the technological country like Britain and the United States，the cBN synthesis technology is still backward， which only Can product low—grade cBN and the high-grade cBN abrasive mainly rely on import．The research for the synthesis process of bulk particle cBN single crystal is conducive to the application and development of cBN material in abrasive industry and other fields， which Call improve the competence of the cBN material synthesis technology in our country． In this paper,the cBN single crystals are synthesized with the hexagonal boron nitride (hBN)as raw material，and Li3N，Ca3N2 as the catalysts respectively under the condition of high temperature and high pressure(HPrrr)，and the optimal process conditions is obtained by changing the parameters of pressure，power and time in the synthesis process．And referring to the method of diamond synthesis process，the bulk particle