TMPAC-AlCl3离子液体电镀铝研究-JournalofNortheasternUniversity.PDFVIP

第3 1 卷第8期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol 3 1, No. 8 2 0 10 年 8 月 Journal of Nort heastern U n vers ty( N atural Sc ence) A ug. 2 0 1 0 TMPAC-AlCl 3 柳 泉, 刘奎仁, 韩 庆, 涂赣峰 ( , 110004) : T M PAC- AlCl3 , ; , , 2 X X , 15 mA / cm , 30 m n , , 92%, A lCl3 A l , , ; 17 m , : ; ; ; ; : T G 174 . 441; T Q 153. 1 : A : 1005- 3026( 2010) 08- 1149- 04 Study on A-l Electrodeposition from TMPAC-AlCl Ionic 3 Liquids LI U Quan, LI UKui-ren, HAN Qing, T U Gan-f eng ( School of M ater als M etallurgy, Northeaster n U n v ers ty, Shenyang 110004, Ch na. Correspondent : L IU Ku- r en , prof essor, E- ma l: l ukr @ smm . neu. edu . cn) Abstract: A l plat ng w as electrodepos ted on cupron ckel alloy as substrate n the tr met hy-l pheny-l ammon um chlor de and anhydrous alum num chlor de ( T MPA C-A lCl3 ) quaternary ammon um room t emperat ure on c l qu ds w t h benzene used as solub l z ng ass stant . T he eff ect s of current dens t y and plat ng t me on surface m croscop c morphology and cat hod c current eff c ency were st ud ed. T he corros on res stance of t he as- depos t ed Al layer was evaluated by potent odynam c polar zat on measurement s. Moreover, scann ng electron m croscope, energ y d spers on X- ray spectrometer and X- ray d f fract on w ere used to charact er ze the samples. T he