卷烟烟气重要酸性香味成分的分离制备与鉴定.pdf

烟草科技/ Tobacco Science Technology 烟草化学/ Tobacco Chemistry 2013 年第 10 期（总第315 期） 卷烟烟气重要酸性香味成分的分离制备与鉴定 1,2 1 *1 1 2 米冠杰 ，顾文博 ，孙文梁 ，刘百战 ，张祥民 1. 上海烟草集团有限责任公司，上海市杨浦区长阳路717 号 200082 2. 复旦大学化学系，上海市杨浦区邯郸路220 号 200433 摘要：为确定卷烟烟气中重要酸性香味成分的组成和作用，以津巴布韦优质烟叶烟气粒相物为对象，建 立了烟气重要酸性香味成分的中压、高压两级液相色谱分离制备方法。并分别对两级馏分进行了卷烟感 官评价。结果表明：①分离制备的饱和酸类、不饱和酸和芳香酸类是烟气中的重要酸性香味馏分；②上 述饱和酸类、不饱和酸和芳香酸类馏分可显著提升卷烟品质；③仅存在于卷烟烟气中的丙烯酸和3- 丁烯 酸对卷烟的香吃味有明显影响。 关键词：卷烟；烟气；酸性香味成分；气相色谱- 质谱联用；感官评价；卷烟风格特征 中图分类号：TS411.2 文献标识码：A 文章编号：1002-0861 （2013 ）10-0049-06 Preparation and Identification of Important Acidic Aromatic Components in Mainstream Cigarette Smoke 1, 2 1 * 1 1 2 MI Guanjie , GU Wenbo , SUN Wenliang , LIU Baizhan , and ZHANG Xiangmin 1. Shanghai Tobacco Group Co., Ltd., Shanghai 200082, China 2. Department of Chemistry, Fudan University, Shanghai 200433, China Abstract: In order to identify the constituents and functions of the important acidic aromatic components in cigarette mainstream smoke, a method for separating and preparing the important acidic aromatic components by two-level, mid- and high-pressure, liquid chromatography was developed using the particulate matters in mainstream smoke of fine Zimbabwe tobacco leaves as objects. The sensory quality of cigarettes containing each distillate was evaluated. The results showed that: 1) The saturation acids, unsaturated acids and aromatic acids obtained with this method were the important acidic aromatic components in mainstream cigarette smoke. 2) The acidic distillates mentioned above could improve cigarette quality obviously. 3) Propenoic acid and 3-butenoic acid, which were only found in cigarette smoke, imparted an obvious influence on the aroma and taste of cigarettes. Keywords: Cigarette; Mainstream smoke; Acidic aro