多孔钙钛矿型纳米材料的制备及其电流变性能研究分析化学专业论文.docxVIP

摘要所制备的钛酸钡电流变液具有相当低的电流密度。拥有大比表面积的钛酸钡粉末 摘要 所制备的钛酸钡电流变液具有相当低的电流密度。拥有大比表面积的钛酸钡粉末 制备的电流变液的屈服应力最大值能达到3kPa，这比传统纯钛酸钡晶体粉末制 各的电流变液的屈服应力要高得多(低于lkPa)。 最后，在制备纳米多孔钛酸钡(BaTi03)晶体粉末的基础上，将煅烧温度降 低到350℃煅烧钛酸钡凝胶制备了Ba．Ti．O纳米材料；并且对Ba．Ti．O纳米材料 与掺杂不同比例极性小分子硫脲的Ba．Ti．O材料所制备的电流变液的流变性能进 行了比较研究。结果表明，在外加电场E=3．5kV／mm时，掺杂硫脲量为15％的 Ba-Ti．O纳米材料电流变液的屈服引力可以达到5．7 kPa，大约是未掺杂硫脲 Ba-Ti．O纳米材料的9倍。掺杂极性小分子硫脲对Ba-Ti．O纳米材料的电流变效 应有很大影响。 关键词：溶胶．凝胶，钛酸钡，钛酸锶，电流变液，超声辐射法，纳米多孔材料 Ⅱ AbstractABSTRACT Abstract ABSTRACT Eletrorheological fluid(ERF)is a class of smart materials which is composed of dielectric particles from nano—sized to micro．sized suspended in insulating medium． The typical feature of ERFs is that apparent viscosity can be experienced a rapid， reversible change by applying all external electric field．These characteristics call be defined by using the formula as follows：％=r／o+At／=7／o+TE／y(％is the apparent viscosity with applying all external electric field，琉is the apparent viscosity in the absence of electric field strength，A r／is the viscosity which caused by applying external electric field，f is the shear stress，y is shear rate)．As a result of the ability to control the apparent viscosity electrically,ERFs are considered to have many potential applications in the field of industry and engineering．Thus，the main purpose of this thesis is that preparation of novel electrorheological materials．In this thesis，nanoporous SrTi03 and BaTi03 materials were prepared，the relationship between the electrorheological properties and surface areas and porous structure were studied，finally the influence of polar molecular thiourea-doped on the electrorheological properties was also studied。The detailed research contents described as follo．ws： Firstly,nanol苫orous strontium titanate(SrTi03)crystals with di疗宅r．ent novel morphologies and crystalline shapes were prepared by a facile and rapid ultrasound irradiation method，using Ti(OBu)a and Sr(OH)2．8H20 as starting materials．The influences of the ultrasonic time，power and pH va