二氧化钛和氧化锌纳米材料的制备和性质研究凝聚态物理专业论文.docxVIP

2 2 扬州人学硕十学位论文 是由于Burstein．Moss效应。 ZnO掺Ag纳米粉体是以氨水为矿化剂通过水热法合成。XRD显示样品为纯ZnO 粉体，Ag未能掺入Zn0晶格。PL谱显示水热合成时]JH,K．Ag离子有助于样品的紫外 发光并抑制可见发光，表明Ag离子有助于提高ZnO纳米粉体的结晶度并减少缺陷。 进一步分析表明当氨水浓度适合乙酸锌水解晰一已经形成了[Ag(NH3)2]+，利用水 合肼缓慢释放NH4+的特点代替氨水作为矿化剂，虽然避免了[Ag(NH3)2]+形成，也 只能得至UZnO和Ag的混合物。 施志明二氧化钛和氧化锌纳米材睾遵的制备和性质研究 施志明二氧化钛和氧化锌纳米材睾遵的制备和性质研究 3 Abstract This thesis is divided into two parts．Part one，different crystal—type Ti02 have been prepared as the starting material for preparing Bi4Ti30I 2 by hydrothermal method and micro—structure of Bi4Ti3012 as prepared have been studied．The differences in the outcome of solid-state reactions using the different phases of a particular starting material are of great interest for the materials science community．Part two，the effects of luminescence properties on Ag doped ZnO nanopowders and nanocrystalline thin films have been studied，for its’considerable guidance significance on solving issues of luminescence mechanism． We changed type of Ti02 from．anatase to brookite under the method of hydrothermal synthesis，through controlling the concentration of NaOH mineralizer in the process of hydrolysis of the Ti(S04)2 to metatitanic acid．Further studies have shown that the temperature requirements of hydrothermal synthesis of brookite-type Ti02 is much higher than anatase-type Zi02 because TiD bond of hrookite—type T_i02_is more complex．Then，bismuth。titanate submicron—rods have been synthesized by a hydrothermal method using anatase and brookite nanocrystallites， respectively, as precursors．The results of XRD，SAED and Raman spetra indicate that two samples can be indexed to the salTle Bi4Ti3012 phase．The corresponding products，a-and b-Bi4Ti30i2 submicron—rods，have distinct differences in structure．The cause for the shift of diffraction peaks is that the amount of Bi intercalated into anatase Ti02 is larger than that into brookite Ti02 under the same conditions．The multiple types of reserved short Ti——o bonds in b-Bi4Ti3012 confined the growth of submicron-rods along