低阶煤制水煤浆表面吸附特性研究化学工程专业论文.docxVIP

摘要本文通过研究添加剂溶液的表面张力、pH值、临界胶柬浓度、特性粘度与吸附特性和水煤 摘要 本文通过研究添加剂溶液的表面张力、pH值、临界胶柬浓度、特性粘度与吸附特性和水煤 浆成浆性之间的匹配规律，构建了宁夏低阶煤的添加剂筛选方案，确定了复配添加剂的配方，对 宁夏低阶煤添加剂的筛选、复配添加剂配方的确定具有重要的意义。具体结论如下： (1)萘磺酸盐．甲醛缩合物系添加剂在10种煤表面均表现出较大的吸附量，对煤种的适应性 强，将萘磺酸盐．甲醛缩合物与其他添加剂复配可以改善添加剂的性能。由于木质素磺酸盐系添加 剂在煤表面的极限吸附量差异较大对煤种的适应性较差，但因其价格低廉与其他添加剂复配可降 低制浆成本。当萘系添加剂与木质素磺酸盐添加剂质量比为2：1时，成浆效果良好。通过对比添 加剂的极限吸附量，NDF相对于前两种添加剂在10种低阶煤表面的吸附量均较小，此类添加剂 对宁夏低阶煤的适应性较差。 (2)表面张力是表面活性剂类物质的重要物理参数，其大小的不同影响添加剂的表面活性， 因此可以利用表面张力对添加剂进行评价。当不同添加剂的浓度均为O．1 g·mL～，若某种添加剂 溶液的表面张力为55 naN·mq-65 mN·in1时，则该种添加剂与低阶煤较匹配故成浆效果较好。成 浆性实验表明，当不同添加剂溶液的浓度均为o．1 g·mL4时，若测得的其pH值在7．65～8．7范围 内，则添加剂的加入使成浆性得到明显改善。 (3)成浆性实验表明，水煤浆添加剂影响煤的棒磨效果。煤粒子过筛率结果表明，加入萘 系添加剂可使粒径小于200目的粒子产出率提高9‰木质素磺酸盐系添加剂则使其产出率降低 5％。通过改变这两类添加剂的加入量可为实际生产中因粗粒子引起的跑浆问题提供新的解决方法。 关键词：水煤浆，吸附，添加剂，成浆性能 万方数据 AbstractIn Abstract In this paper,additive evaluation scheme for Ning)【ia low rank coal was formulated by studying matching principle surNee tension，pH，critical mieelle concentration，intrinsic viscosity,adsorption of the additive solution and coal water slurry(cws)property．The study has important significance for additive evaluation and the ratio of additives has been defined．The conclusions as follows： (1)Naphthalene sulfonate—formaldehyde additive has better adsorption in 10 coals with good adaptability．By mixing naphthalene sulfonate-formaldehyde with other additives could improve the performance of additives．Because ignin sulfonate additive has large limit adsorption differential in coal surface that this additive has poor adaptability．Because of the low price，mixed additives of ignin sulfonate reduce puIp costs．When the mass ratio of naphthalene sulfonate-formaldehyde and ignin sulfonate additive is 2：1，the slurryability be significantly improved．By comparing the limit adsorption amount of three，NDF showed poor adaptability for low rank coal in Ningxia． (2)Surface tension is an important physical parameters of surfactant，and the surfactant of additive WaS affected by that．So experiment Can surface tensio