螯合剂和表面活性剂强化巨菌草修复铅镉复合污染土壤研究环境工程专业论文.docxVIP

广东工业大学硕士学住论文(6)采用蔬菜基地田间实验，分别添加10．0 广东工业大学硕士学住论文 (6)采用蔬菜基地田间实验，分别添加10．0 mmol·L以的EDTA和柠檬酸强化巨 菌草修复污染土壤。酸溶态Pb和Cd变化最为显著，在根际土壤中的含量较非根际土 壤显著增加，其中EDTA强化处理分别增加了26．78％和9．13％，柠檬强化处理分别增 加了25．41％和2．23％。在EDTA和柠檬酸作用下，Pb和Cd在巨菌草体内的累积量显 著增加，且EDTA效果显著于柠檬酸，较对照组分别增加了92．43％和26．79％。 关键词：土壤；重金属污染；表面活性剂；螯合剂；植物修复 II 万方数据 ABSTRACTAB ABSTRACT AB STRACT Great achievement has been obtained on the remediation of heavy metal contaminated soil by adding chelant and surfactant．Nemerow index was used to evaluate the soil pollution situation by heavy metals which were resulted from the domestic waste fertilizer，and ．selected the target heavy metal as our studying object．The optimal activation time and adding doses were obtained though static activation experiments．It indicated that TX-100 and tea saponin could enhance adsorption of Pennisetum spp．on soil Pb and Cd in pot experiment,EDTA and citric acid to could enhance the adsorption ability of Pennisetum spp． on soil Pb and Cd in the field experiment．It could be concluded that： (1)The Nemero index(NO Was selected as parameter to estimate the pollution situation of soil heavy metals of the studying area．It indicated that soil showed obvious contamination from As，slightly pollution from Hg,moderate from Pb and serious pollution from Cd，where the NI of soil Pb and Cd were 2．69 and 9．1 7，respectively． (2)The pH value of soil solution decreased 0．1 5—0．99 unit after 7-day static experimental activation treated by EDTA and citric acid．While the pH value of soil solution decreased O．1 1-0．83 unit after a 14-day static experimental activation treated by TX-100 and tea saponin．After that the soil pH increased gradually and tended to be constant after 28一day static experimental activation．Except for TX一100，when treated by the static experimental activation，the bioavailable state of Pb and Cd increased significantly at the 7th day,and peaked at the 28血day． (3)After 28-days’static experimental activation．the acid soluble state of soil Pb and Cd increased with