隔离器用高性能微波吸收材料的研制材料学专业论文.docxVIP

西南科技大学硕士研究生学位论文 西南科技大学硕士研究生学位论文 第l页 摘 要 本文针对目前国内隔离器负载用微波吸收材料存在的主要问题， 提出了隔离器负载用微波吸收材料的设计思路。对羰基铁粉进行 KH．560硅烷偶联剂的改性，采用热重、红外光谱等手段对改性后的 粉体进行了表征。以环氧树脂为基体，改性前后羰基铁粉为吸收剂， 采用真空浇注的方法制备复合微波吸收材料，对吸收体的制备工艺进 行了初步探讨，分析了其影响因素，通过实验确定其最佳配方和最优 工艺条件。测试了吸收体的体电阻率、击穿强度、吸收损耗、热变形 温度以及使用该材料的隔离器的性能，并从材料的微观结构进行了分 析讨论。主要结果结论如下： (1)改性后的羰基铁粉表面形成了si—O分子包覆层，提高了 羰基铁粉的抗氧化性和绝缘性以及羰基铁粉在有机基体中的分散稳 定性，改善了羰基铁粉与基体材料的界面相容性和粘结强度。 (2)环氧树脂固化成型影响因素有g①胶液与羰基铁粉的相容 性，本文通过硅烷改性以及调整胶液配方来改善它们之间的相容性。 ②物料的流动性，主要是胶液的粘度，取决于胶液配方和环境温度。 ③界面层结构形成，取决于胶液配方和体系的热历程，而且还与羰基 铁粉的表面性能密切相关。 (3)改性后吸收体相对于改性前吸收体，热变形温度由1 3 5℃ 提高到l 70℃，击穿强度达700V／mm，电阻率为4．99 1 0sQ·cm， 6—1 8GHz频率范围内吸收损耗在1．8～7．8dB／mm之间。隔离器负载中 使用该材料，器件驻波比冬1．6时，插入损耗芝．1．2dB，隔离度茎．1 0dB， 相对带宽为l 00％，吸收体已经满足6～1 8GHz边导模隔离器的性能要 求。 关键词：微波吸收材料 羰基铁 硅烷偶联剂 隔离器 负载 Ab Ab st r a ct． This research aimed at solving the main problems in the microwave absorbing materials for domestic isolator load at present the view of absorber’S design was put forward．Carbonyl iron powder was modified by silane coupling agent(KH一5 60)，and the modified cafbonyl iron powder was characterized by TG，IR etc．Carbonyl iron powder／epoxy resin composite material was prepared by vacuum casting using epoxy resin as matrix and carbonyl iron powder as absorbing agent，the preparation process of the absorber were discussed， the influence factor were analyzed，through experiments the appropriate formula and the process condition were determined·The elec：tric volume resi stivity，voltage breakdown strength，absorption loss of the absorber and thermal deformation temperature were measured’ and the characteristics of isolator using the prepared absorber were tested．These properties were discussed；the main results are as follows： (1)Si．0 molecular layer were formed in the surface of the modified carbonyl iron powder，the inoxidizability and insulativity of carbonyl iron powder and the dispersivity of carbonyl iron powder 1n epoxy resin matrix were improved，and the interfacial compatibility and bond strength of carbonyl iron powde