纳米AuTiO2薄膜真空紫外光催化降解甲醛-北京玛格泰克科技发展.PDFVIP

中国环境科学 2010,30(11) ：1441~1445 China Environmental Science 纳米 Au/TiO2 薄膜真空紫外光催化降解甲醛 * 李 佳,傅平丰,张彭义 (清华大学环境科学与工程系,环境模拟与污染控制国家重点联合实验室,北京 100084) 摘要：为提高真空紫外光催化对甲醛的去除率并降低副产物 O3 的浓度,采用低温吸附法在 TiO2 薄膜上负载纳米 Au.研究比较了 UV254nm 光催化(TiO /UV) 、真空紫外光降解(VUV)、真空紫外光催化(TiO /VUV)等 3 种方法对低浓度甲醛的降解效果.结果表明,TiO /VUV 对甲醛 2 2 2 的去除率显著高于 VUV 和 TiO2/UV.TiO2 表面负载纳米 Au 粒子能促进光生电子和空穴的分离.因此,在真空紫外光催化降解过程中, Au/TiO2 不仅提高甲醛的降解率,还显著分解副产物臭氧,使尾气臭氧浓度降低 32%.而且 Au/TiO2 薄膜在真空紫外光催化过程中具有很好的 稳定性. 关键词：真空紫外光催化；甲醛；纳米金；臭氧分解；室内空气污染 中图分类号：X701.1 文献标识码：A 文章编号：1000-6923(2010)11-1441-05 Vacuum ultraviolet photocatalytic degradation of formaldehyde and ozone decomposition by Au/TiO2 * nanocomposite film. LI Jia, FU Ping-feng, ZHANG Peng-yi (State Key Joint Laboratory of Environment Simulation and Pollution Control, Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China). China Environmental Science, 2010, 30(11)：1441~1445 Abstract ：To increase VUV (vacuum ultraviolet) photocatalytic efficiency for removing formaldehyde and decomposing its byproduct, i.e. ozone (O3), Au nanoparticles was supported on TiO2 nanocomposite film with low-temperature adsorption method. Three methods, i.e. UV photocatalysis (TiO /UV), VUV photolysis (VUV) and VUV 254nm 2 photocatalysis (TiO2/VUV) were compared to degrade low concentration formaldehyde in the gas phase. The results showed that the removal ratio of formaldehyde in the TiO /VUV process was much higher than that in the TiO /UV or 2