缓冲体系中高热和水热稳定性的MCM.pdf

2005 年第 63 卷 化 学 学 报 Vol. 63, 2005 第 13 期, 1241～1244 ACTA CHIMICA SINICA No. 13, 1241～1244 ·研究简报· 缓冲体系中高热和水热稳定性的 MCM-48 介孔分子筛的合成 孔令东 a 刘 苏 b 颜学武 a 贺鹤勇 a 李全芝*,a (a 复旦大学化学系和上海市分子催化及创新材料实验室 上海 200433) (b 复旦大学环境科学与工程系 上海 200433) 摘要 利用混合阳离子-非离子表面活性剂为模板剂在缓冲体系中成功地合成出具有高热和水热稳定性的 MCM-48 介 孔材料. 通过 XRD, N2 吸附-脱附, 29Si MAS NMR 和 31P MAS NMR 等手段对样品进行了表征. 结果表明, 合成的 MCM-48 材料具有高的比表面积和高度有序的孔道系统. 样品在空气中于 900 ℃下焙烧 15 h 和在 600 ℃ 100%水蒸气 下处理 8～10 h, 仍能保持良好的立方孔道结构, 显示很高的热稳定性和极好的水热稳定性. 关键词 缓冲体系; MCM-48; 混合表面活性剂; 介孔材料 Synthesis of Highly Thermally and Hydrothermally Stable MCM-48 in Buffer Solution KONG, Ling-Donga LIU, Sub YAN, Xue-Wua HE, He-Yonga LI, Quan-Zhi*,a a ( Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433) b ( Department of Environmental Science and Engineering , Fudan University, Shanghai 200433) Abstract Mesoporous MCM-48 with high thermal and hydrothermal stability has been successfully syn- thesized in buffer solution by mixed cationic-nonionic surfactant templating pathway. The synthesized mate- 29 31 rial was characterized by XRD, N2 adsorption-desorption isotherms, Si and P MAS NMR. The character- istic results showed that the MCM-48 material possessed high specific surface areas and well-ordered chan