重铬酸钾法快速测定中药蛇含石全铁含量.pdf

·60· Chinese Journal of Information on TCM Feb.2013 Vol.20 No.2 重铬酸钾法快速测定中药蛇含石全铁含量 路立峰,李桂荣,张立庆,任玉红,丛淑芹,王华丽 山东药品食品职业学院,山东 威海 264210 摘要：目的 建立蛇含石全铁含量的快速测定方法。方法 通过对供试品处理方法的考察,建立三氯化钛-重铬 酸钾容量法测定蛇含石全铁含量的方法。结果 经处理的药材细粉在优选溶剂中仅需十几分钟即可完全溶解,方法加 样回收率为97.54%～101.72%,RSD＝1.33%,重复性试验RSD＝0.59%,精密度试验RSD＝0.23%,测得样品中全铁平均含 量为71.50%。结论 本方法快速、准确,为制定其质量标准提供了依据。 关键词：蛇含石；灼烧；重铬酸钾容量法；含铁量 DOI：10.3969/j.issn.1005-5304.2013.02.022 中图分类号：R284.1 文献标识码：A 文章编号：1005-5304(2013)02-0060-02 Rapid Determination of Total Iron Content in Limonite by Potassium Dichromate Method LU Li-feng, LI Gui-rong, ZHANG Li-qing, REN Yu-hong, CONG Shu-qin, WANG Hua-li (Shandong Drug and Food Vocational College, Weihai 264210, China) Abstract ：Objective To establish a method for the determination of total iron in limonite. Methods The processing method of the drug sample was investigated, and the potassium dichromate method for the determination of the total iron in limonite was established. Results The processed drug powder could dissolve in selected reagent within about ten minutes. The recovery rate was 97.54%－101.72%, with RSD of 1.33% (n ＝9). RSD of reproduction was 0.59%, and RSD of precision was 0.23% (n ＝6). The average content of total iron in sample was 71.50% with RSD of 0.16% (n ＝6). Conclusion The method was rapid and accurate, and provided a basis for establishing the quality standard of limonite. Key words ：limonite；heating；potassium dichromate method；content of total iron 蛇含石又名蛇黄,《唐本草》载“圆重如锡,黄黑青杂色”, 钾、10%氯化亚锡。 《本草纲目》中亦记载其味甘性寒,有安神镇惊、止血定痛之效。 2.2.2 方法 称取药材粉末0.2 g,转移至250 mL锥形瓶中, 笔者查阅相关资料[1-4],拟通过对蛇含石样品的处理,用重铬酸 加少量水润湿,加