微波皂化法制备紫胶桐酸-食品科学.PDFVIP

※工艺技术 食品科学 2011, Vol. 32, No. 14 79 1,2 1, 2 1 1,2 刘世平 ，张 弘 * ，周梅村 ，郑 华 ，李 凯 (1. 中国林业科学研究院资源昆虫研究所，云南 昆明 650224 ；2. 昆明理工大学化学工程学院，云南 昆明 650224) 采用常压微波法对天然紫胶树脂皂化，后经盐析、结晶等一系列操作，制备紫胶桐酸。单因素试验考 察微波功率、碱液质量分数及微波时间 3 个主要因素对紫胶桐酸得率的影响，并以紫胶桐酸得率为响应值，采用 响应曲面法对皂化工艺进行优化试验。结果表明，在微波功率 200W 、碱液质量分数25.8% 、微波时间31min 条 件下，紫胶桐酸得率最大，达到 2 1 . 9 0 % 。由红外光谱、X 射线衍射、差示扫描量热、扫描电镜等表征可知， 微波皂化法制备的紫胶桐酸结晶均匀、杂质较少。微波皂化法制备紫胶桐酸简单易行，能有效缩短制备时间，且 得率较高。 微波；皂化；紫胶桐酸；响应曲面法 Microwave-assisted Saponification for the Preparation of Aleuritic Acid from Lac Resin 1,2 1, 2 1 1,2 LIU Shi-ping ，ZHANG Hong *，ZHOU Mei-cun ，ZHENG Hua ，LI Kai (1. Research Institute of Resources Insects, Chinese Academy of Forestry, Kunming 650224, China； 2. Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650224, China) Abstract ：In order to prepare aleuritic acid, lac resin was saponified under microwave assistance, followed by salting out and crystallization. The effects of three major process conditions including microwave power, NaOH concentration and microwave treatment time on aleuritic acid yield were explored by one-factor-at-a-time experiments. Further, the three conditions were optimized by response surface methodology. The optimal saponification conditions were microwave treatment power of 200 W, NaOH concentration of 25.8% and microwave treatment time of 31 min. Under the optimal saponification conditions, the highest yield of aleuritic acid was achieved to be 21.90%. The aleuritic acid obtained was characterized by infrared spectroscopy, X-ray di