碳化混凝土硫酸钠盐结晶破坏-硅酸盐学报.PDF

第 45 卷第 11 期 硅 酸 盐 学 报 Vol. 45 ，No. 11 2 0 1 7 年 1 1 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY November ，2017 DOI ：10.14062/j.issn.0454-5648.2017.11.08 碳化混凝土硫酸钠盐结晶破坏 刘赞群，候 乐，邓德华，张丰燕，胡文龙 ( 中南大学土木工程学院，长沙 410075) 摘 要：研究了不同水灰比、不同粉煤灰、矿渣掺量混凝土试件快速碳化 10 d 和 20 d 后，半浸泡在 10%硫酸钠溶液中，在 恒温恒湿环境下[(20±1)℃，相对湿度 RH(60±5)%] ，混凝土试件水分蒸发区的破坏特征及其质量损失率随侵蚀时间的变化规 律。结果表明：混凝土碳化深度越大，混凝土破坏越严重；用粉煤灰和矿渣取代水泥加剧混凝土碳化，导致混凝土破坏更严 重；碳化混凝土中发生的硫酸钠结晶是混凝土发生破坏的原因。 关键词：硫酸盐侵蚀；硫酸盐物理侵蚀；硫酸钠；混凝土碳化 中图分类号：TU528 文献标志码：A 文章编号：0454–5648(2017)11–1621–08 网络出版时间：2017–10–09 13:56:00 网络出版地址：/kcms/detail/1 1.2310.TQ1356.019.html Sodium Sulfate Salt Crystallization Distress on Carbonated Concrete LIU Zanqun , HOU Le, DENG Dehua , ZHANG Fengyan, HU Wenglong (School of Civil Engineering, Central South University, Changsha 410075, China) Abstract: Concrete specimens with different water-cement ratios and different dosages of fly ash and slag were carbonated for 10 d and 20 d and then partially exposed into 10% Na SO solution under the condition of (20 ±1)℃, (60 ±5)% relative humidity. The 2 4 mass loss rate of specimen was measured and the visual observation of damaged concrete was compared. The results show that the concrete carbonation accelerates its failure. The evaporation zone of concrete specimens with fly ash and slag was damaged more severely rather than the ordinary concrete due to the greater carbonation depth. Based on the results by X-ray diffraction, the sodium sulfate crystallization in the carbonated concrete causes the concrete failure. Keywords: sulfate attack on concrete; physical sulfate attack; sodium sulfate, concrete carbonation 当普通硅酸盐水泥