芳纶纤维表面银金属化的性能-材料研究学报.PDFVIP

第31 卷 第8 期 Vol. 31 No. 8 2017 年8 月 CHINESE JOURNAL OF MATERIALS RESEARCH Aug. 2017 芳纶纤维表面银金属化的性能 余 帆 滕翠青 秦明林 刘百花 张 康 倪加其 余木火 (东华大学材料学院 上海 201620) 摘要用NaOH 粗化处理芳纶纤维，然后用化学镀方法实现了芳纶纤维表面Ag 金属化。使用扫描电子显微镜 (SEM)、原子力显微镜(AFM)和X 射线光电子能谱仪(XPS)等手段对纤维的表面形貌和元素组成进行了表征， 使用X 射线衍射仪(XRD)分析了镀银前后纤维的晶体结构变化，使用纤维强伸度仪和热重分析仪(TG)测量了 芳纶纤维在镀银前后的力学性能和热稳定性，用万用表测试了镀层的导电性能。结果表明：Ag 金属层均匀致 密地包裹在纤维的表面，结合牢固度较高。镀银使纤维的热稳定性有所提高，对力学性能的影响较小，电阻达 到0.52 Ω/cm ，在冷热水循环和盐水环境下银层的稳定性较好。 关键词 材料表面与界面，芳纶纤维表面银金属化，化学镀，氢氧化钠 中图分类号 TB333 文章编号 1005-3093(2017)08-0585-06 Performance of Silver-deposited Aramid Fibers YU Fan, TENG Cuiqing, QIN Minglin, LIU Baihua, ZHANG Kang, NI Jiaqi, YU Muhuo (College of Materials Science Engineering, Donghua University, Shanghai 201620, China) Correspondent: TENG Cuiqing, Tel: E-mail: cqteng@dhu.edu.cn Supported by National Basic Research Program of China (No. 2011CB606100) Manuscript received 2016-09-18, in revised form 2016-12-10 ABSTRACT Silver nano-particles were deposited on the surface of aramid fibers by a two-step pro- cess i.e. firstly coarsening the surface of aramid fibers with sodium hydroxide and then Ag electroless plating. The Ag-plated aramid fibers were characterized by scanning electron microscope (SEM), atomic force microscope (AFM), X-ray photoelectron spectrometer (XPS) and X-ray diffractometer (XRD). The mechanical properties, thermal stability, and electrical resistance of the Ag-plated aramid fibers were ex- amined by thermogravimetric analyzer (TG) and dig