有机胺催化双酚A与碳酸二苯酯熔融酯交换动力学-高校化学工程学报.PDF

20 6 No.6 Vol.20 2006 12 Journal of Chemical Engineering of Chinese Universities Dec. 2006 1003-9015(2006)06-0945-06 A , , , ( , 510640) A HPLC HPLC A A TQ323.41 TQ320.62 A Melt Transesterification Kinetics of Bisphenol A and Diphenyl Carbonate Catalyzed by Organic Amines QIN Ji-chen, XIE Xiao-li, CAO Xian-wu, QU Jin-ping (National Engineering Research Center of Novel Equipment for Polymer Processing, The Key Laboratory of Polymer Processing Engineering, Ministry of Education, South China University of Technology, Guangzhou 510640, China) Abstract: The melt transesterification kinetics of bisphenol A and diphenyl carbonate catalyzed by tri-n-butylamine, tetra-n-butylammonium hydroxide and tetra-n-butylammonium chloride, respectively, was studied in a batch reactor without regard to the elementary catalyzing mechanism. Based on the functional group model, an integral rate equation correlating the molar concentration of phenol with the reaction time was deduced. According to the obtained integral equation, the rate constants and equilibrium constants were calculated from the curves of phenol concentration in reaction samples versus reaction time, in which the content of phenol in reaction mixtures was determined by high-performance liquid chromatography (HPLC). The species molar concentrations of oligomers formed in the reaction were obtained by solving the differential equations derived from the molecular species model, and the results are consistent with the analysis of HPLC. The formation of oligomer fro