材料表征教学资料diffraction.ppt

Dr. Di Wu, Nanjing University * Angle width of diffraction Angle width is the full width of half maximum for a diffraction peak. Consider a small deviation from the reciprocal vector, ?i, Dr. Di Wu, Nanjing University * Angle width of diffraction 为了方便计算，我们把 用 代替 共同点： 它们在 时取最大值 。 当 时， 它们都表现出?函数的特性 曲线下的面积相同，均为 。 Dr. Di Wu, Nanjing University * Angle width of diffraction 如果晶粒是一个平行六面体，三维的长度非别是 N1a，N2b和N3c，AN是对角线的长度，正比于晶粒的大小T。 Dr. Di Wu, Nanjing University * Angle width of diffraction Dr. Di Wu, Nanjing University * Angle width of diffraction Practically, integration width is often used to represent the angle width of diffraction. It is defined as the ratio of integration intensity to maximum intensity of a certain diffraction line. 0 2? Dr. Di Wu, Nanjing University * Angle width of diffraction If the angle slightly deviated from the Bragg’s angle, the phase difference of adjacent planes changes accordingly. A C B 1 1? 2 2? d ? ? ? Dr. Di Wu, Nanjing University * Angle width of diffraction Dr. Di Wu, Nanjing University * Angle width of diffraction if scattering amplitude of a single plane is a, m layers scattering amplitude A should be the intensity is Dr. Di Wu, Nanjing University * Angle width of diffraction Dr. Di Wu, Nanjing University * Angle width of diffraction practically, Dr. Di Wu, Nanjing University * Lattice distortion d0 d uniform distortion ununiform distortion Dr. Di Wu, Nanjing University * Lattice distortion Different ?? values from different part of the crystal, due to ununiform lattice distortion, results in the widened diffraction lines. Dr. Di Wu, Nanjing University * Physical width However, the measured diffraction line width is always larger than physical status could induced. The instrument may have an intrinsic line width. crystal size strain Dr. Di Wu, Nanjing University * Physical width physical line profile: i(?) instrument line profile: i0(?) divide the area under i(?) into a large number of s