反应工程基础（程易）chapter9rtd283507575.pptVIP

Maximum mixedness gives the lower bound on conversion (X) when n1. Mole balance 9.7.3 Segregation vs. maximum mixedness predictions If then O. Levenspiel, P358 (a) (b) (c, d, e) 9.8 Using software packages Read CD. 9.9 RTD and multiple reactions For multiple reactions use an ODE solver to couple the mole balance equations, dCi/dt=ri (where ri is the net rate of reaction). Segregation model Maximum mixedness model Summary 1. E(t)dt: fraction of material exiting the reactor that has spent between time t and t+dt in the reactor. 2. The mean residence time 3. The variance about the mean residence time is is equal to the space time ? for constant volumetric flow, ? = ?0 4. The cumulative distribution function F(t) gives the fraction of effluent material that has been in the reactor a time t or less: 5. The RTD functions for an ideal reactor are Plug flow CSTR Laminar flow 6. The dimensionless residence time is 7. The internal-age distribution, [I(?), ?], gives the fraction of material inside the reactor that has been inside between a time ? and a time ?+d? 8. Segregation model For multiple reactions 9. Maximum mixedness: For multiple reactions 9.3.3 Other moments of the RTD The second moment about the mean is the variance The third moment, skewness The two parameters most commonly used to characterize the RTD are ? and ?2. 9.3.4 Normalized RTD function, E(?) ?: represents the number of reactor volumes of fluid based on entrance conditions that have flowed through the reactor in time t. Why we use a normalized RTD? The flow performance inside reactors of different sizes can be compared directly. Example: all perfectly mixed CSTR: 9.3.5 Internal-age distribution, I(?) ?: represents the age of a molecule inside the reactor I(?)??: the fraction of material inside the reactor that has been inside the reactor for a period time between ? and ?+ ?? CSTR: P633推导过程 9.4 RTD in ideal reactors 9.4.1 RTDs in batch and plug-flow reactors Plug flow reactor: Properties of Dirac delt