剪切力场下不同分子量级别腐殖酸铝盐絮凝体形态学研究-环境科学专业论文.docxVIP

西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 Study on the morphology Al-humic flocs under different molecular weight distribution in shear force field Speciality: Environmental Science Author: Zhang Kun Adviser: Prof. Pengkang Jin ABSTRACT This paper selected lake bottom sediment as raw material, the use of IHSS recommended method for purification of the sediment to obtain natural humic acid,humic acid purified by means of elemental analysis(EA) is mainly composed of the elements of C,O,N,H,S,about 98% of the total mass of humic acid. By ultrafiltration and organic carbon mass balance calculations to separate the humic acid of different molecular weight, the results show that the humic substances which molecular weight greater than 30000 up to about 41% of the total molecular weight,and the substances of molecular weight less than 1000 at least,accounting for 6.7%of the total.Substances of four molecular weight level of 10000~30000、5000~10000、3000~5000、1000~3000 account for 11.5%,13.3%,11.8%,15.7% of the total respectively. Determination of aluminum flocs’ size,settling velocity and other parameters to calculate the fractal dimension and strength through microscopic photography, image analysis and particle image velocimetry, and use the fractal theory to discuss the structural characteristics of humic flocs which formation in the cogulation with aluminum sulfate as coagulant and humic acid of different molecular weight level under the shear force field.The results show that the fractal dimension of flocs decrease with the molecular weight decreases.Under the conditions of weakly acidic(pH=5.0),the range of flocs’ fractal dimension of three level which molecular weight greater than 30kDa,10kDa～30kDa ,5kDa～10kDa was 1.83~1.94,1.8~1.87,1.74~1.81 respectively, but the value was ranging from 1.77 to 1.78,1.77 to 1.83,1.71 to 1.78 respectively at neutral (pH=7.0). Under weakly acidic conditions,the change of HA flocs’ fractal dimension with the in