剪切对iPP等温结晶的影响-材料加工工程专业论文.docxVIP

ABgn认(可ABSTRACT ABgn认(可 ABSTRACT The structure，morphology and ultimate properties of semicrystalline polymers ale strongly dependent on the crystallization behavior of them．Whall a semicrystalline polymer is subjected to flow,as invariably happens during processing the crystallization behavior change to some extent．In fact,all the polymers were be sheared in the process ofmanufacturing．In order to understand the crystallization kinetics thoroughly and obtain the better properties，it is needed for US to study the crystallization behavior under flow conditions ofpolymers． In this thesis，the isothermal crystallization COBl8e of isotactic polypropylene(i—PP) on sheafing and the history of shear were studied by rheology method．And all the works as follow：： 1．We studied the influence oftemperature and shear-rate on crystallization induction time by the curve of shear viscidity(Normalforce)versus times．n圮results show that it call晡ng forward the time of shear viscidity(Normalforce)breaking and short the induction time with higher shear rate under isothermal conditions；and it Can bring forward the time of shear viscidity(Normalforce)breaking and short the induction time witIl lower temperature under the same shear-rate conditions． 2．Wb study the effects oftemperature(shear-rate)on the induction time utilizing the curve of induction time versus shear-rote(temperature)．The results show that the induction time changed speedy under higher temperature or lower shear-rate． 3．Studies on induction time depended on the shear viscidity and normalforce we carried out．It is found that we Call token the induction time by viscidity and normalforce． But,the time ofshear viscidity breaking ahead ofthe time ofnormalforce breaking under lower shear-rate and it is oppositional under higher shear-rate． 4．We studied the effect of shearing history on isothermal crystallization process by the curve of shear modulus VglSUS times．The results indicate that the induction time wiU be shorter along with