固载硫酸钛连续催化合成丙酸丁酯.PDF

2005 年 7 月 　　 　化 　学 　工 　业 　与 　工 　程 第 22 卷 　第 4 期 　 July 2005 CHEMICAL 　INDUSTRY　AND 　EN GINEERIN G Vol . 22 　　No . 4 ( ) 　　文章编号 :1004 - 9533 2005 04 - 0275 - 04 固载硫酸钛连续催化合成丙酸丁酯 毛立新 (湖南理工学院化学化工系 ,湖南 岳阳 414000) 摘要 : 以硅胶固载硫酸钛在500 ℃下焙烧改性后的固体酸为催化剂 ,在连续催化反应装置中催化合 成丙酸正丁酯 。并研究了连续催化反应的工艺条件是 :催化剂固载量 02 g [ Ti ( SO ) ]g ( SiO ) ; n 4 2 2 ( ) n ( ) 0 ∶14 ;进料量012 Lh ,丙酸丁酯的收率在 955 %以上 。 丙酸 : 正丁醇 1 关键词 :硫酸钛 ;连续催化反应 ;丙酸正丁酯 ;合成 中图分类号 :TQ22524 + 1 ;O623624 + 1 　文献标识码 :A Synthesis of nButyl Propanoate Continuously Catalyzed by Immobilized Titanium Sulfate MAO Lixin (Department of Chemistry and Chemical Engineering , Hunan Institute Science and Technology , Hunan Yueyang 414000 , China) Abstract :In this paper , nbutyl propanoate was synthesized in a device of continuous catalytic reaction ,by using solid acid catalysts modified from titanium sulfate immobilized on a silica gel and was calcinated at 500 ℃. The continuous catalytic reaction conditions were analyzed and the optimum condition was obtained as follows :catalysts supported is 02 g[ Ti ( SO ) ]g ( SiO ) , n (propanoic acid) : n (butanol) = 10 ∶14 ,amount 4 2 2 of incoming charge is 012 Lh .Under the optimum condition ,the yield of nbutyl propanoate