污水管用树脂混凝土配比与工作特性.DOCVIP

污水管用樹脂混凝土配比與工作特性 The Mix Design and Workability of Polymer Concrete for Sewerage Pipes 研究生：顏崑益 Yen, Kuei-I 指導教授：謝啟萬 Chen, Zhi-Han 【摘要】 樹脂混凝土具有高強度及耐腐蝕等特性，實為污水下水道管材的最佳選擇，但其關鍵配比及生產技術掌控國外，所以本研究採用國內生產的不飽和聚酯樹脂來配製本土化的樹脂混凝土應用於下水道管線，以強度為主要考慮依據尋求最佳配比，對其力學性質、物性、抗化性、彈性模數及波松比進行研究。樹脂混凝土經80 ℃養護的抗壓強度可達990 kg/cm2，吸水率、抗酸、抗鹼腐蝕皆小於0.1 %，而彈性模數在最大負載應力10~60 %範圍內，其彈性模數隨應力增加而降低；當樹脂混凝土承受低負載(最大負載應力20 %)作用時，此時的彈性模數約為10 %最大負載應力對應之彈性模數(約為11.9 GPa)的95 %，其波松比約為0.20，而承受高負載(最大負載應力80 %)狀況時，彈性模數約為10 %最大負載應力對應之彈性模數的76 %，波松比約為0.32；藉由改變硬化劑、促進劑的應用配比以調整可工作時間的長短，當室溫約為25℃時，添加硬化劑(HD/UP)=0.60 %、促進劑(AC/UP) =0.37 %時，其可工作時間約為15分鐘，而隨著增加硬化劑、促進劑的添加比例，可工作時間也隨著縮短，當硬化劑(HD/UP)為0.85 %、促進劑(AC/UP) 為0.57 %時，可工作時間縮短為9分鐘，且室溫每上升1 ℃，膠化溫度約上升1.0~1.4 ℃；最後針對拆模時間與強度關係進行研究，可知樹脂混凝土在30分鐘的拆模強度可達630 kg/cm2以上，而促進劑二甲基苯胺添加量的多寡雖影響樹脂混凝土的短期強度，但對28天強度的影響則不顯著。 關鍵字：樹脂混凝土、下水道管材、不飽和聚酯樹脂 【Abstrace】 Since polymer concrete is a high strength material with an excellent corrosion resistance property, it is considered to be the best selection for sewerage pipes. Currently, foreign countries controlled the raw materials and the mix design of producing polymer concrete (PC). The use of local raw materials to produce polymer concrete for sewerage pipes was investigated. Mix design of high strength PC and its associated engineering properties were studied. The compression strength of 80 oC conditioned PC is more than 990 kg/cm2. The elastic modulus of PC decreased as increasing compression load. The elastic modulus and Poisson’s ratio of PC under 20% and 60% of its maximum compression load are 11.3 and 9.0 GPa, and 0.20 and 0.32, respectively. The gel time and workability of PC can be modified as changing the quantity of promoters and hardeners in the mixture. Working time varied from 9 to 15 minutes as changing the mixture. The gel temperature increased 1.0 to 1.4 oC as increasing 1.0 oC room temperature. The strength of PC would reach 630 kg/cm2 after 30 minutes mixing. The quantity of promoter used in the PC mixture will change its early strength and h