蛇纹石表面特性-硅酸盐学报.PDF

第 45 卷第 8 期 硅 酸 盐 学 报 Vol. 45 ，No. 8 2 0 1 7 年 8 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY August ，2017 DOI ：10.14062/j.issn.0454-5648.2017.08.21 综 合 评 述 蛇纹石表面特性 1 1 2 李桂金 ，赵 平 ，白志民 (1. 中国建筑材料科学研究总院，北京 100024 ； 2. 中国地质大学(北京)材料科学与工程学院，北京 100083) 摘 要：以蛇纹石晶体结构相近的高岭石、理论化学成分相近的滑石为参比对象，分析了3 种矿物的表面基团种类与键强度、 表面酸性来源及零电荷点差异，对比研究了蛇纹石的离子吸附性、有机物吸附行为、与铁基摩擦副作用行为、润湿性等现象， 探讨了各种现象与结构成分间的关系，并提出了蛇纹石等层状硅酸盐矿物表面性质的研究重点。 关键词：蛇纹石；高岭石；滑石；表面特性 中图分类号：P 578.964 文献标志码：A 文章编号：0454–5648(2017)08–1204–07 网络出版时间：2017–07–23 17:55:04 网络出版地址：/kcms/detail/11.2310.TQ1755.014.html Surface Characteristics of Serpentine 1 1 2 LI Guijin , ZHAO Ping , BAI Zhimin (1. China Building Materials Academy, Beijing 100024, China; 2. School of Material Science and Technology, China University of Geoscience (Beijing), Beijing 100083, China) Abstract: The surface groups and bond strength, origin of surface acidity and the point of zero charge of three kinds of minerals (i.e., kaolinite, talc and serpentine) were analyzed. The surface phenomena of serpentine, such as ion adsorption property, organic adsorption behavior, interaction behavior with iron based friction pairs, and wettability were investiaged. The relationships among various phenomena and structural composition were discussed. The review presented some research aspects on the surface properties of layered silicate minerals like serpentine. Keywords: serpenti