基于超顺磁纳米颗粒的磁性纳米线研究-材料科学与工程专业论文.docxVIP

摘 要 一维磁性纳米线由于在细胞操作、微流体以及微观力学等方面的应用潜 力，一直备受关注。为此，人们不断探索简单有效的纳米线组装方法并试图 研究其组装机理。在本研究中，主要采用超顺磁纳米颗粒与常用的同性聚电 解质聚合物作为组装单元，通过自然界常见的静电相互作用组装制备一维磁 性纳米线，并通过改变γ-Fe2O3超顺磁纳米颗粒与阳离子聚电解质聚合物的量 控制溶液电荷比值Z、透析温度T等参数控制纳米线结构与形貌，研究其组装 机理。 本文通过共沉淀法制备的γ-Fe2O3纳米颗粒，采用XRD、VSM、TEM等分 析测试手段对所制备样品进行表征，结果表明该样品具有典型的超顺磁性， 颗粒粒径较为均一，多分散性较小。通过聚丙烯酸对其表面包裹改性后，DLS 结果表明其包裹层厚度约5nm，且包裹后纳米颗粒在水基环境、高浓度盐环 境、细胞培养液环境中具有更优良的胶体稳定性。包裹改性后的γ-Fe2O3超顺 磁纳米颗粒表面带有大量的游离羧基官能团，为其进一步的生物功能化做好 了准备，是理想的生物医药材料前驱体，在核磁共振造影剂、靶向给药、热 疗剂等方面具有广阔的应用前景。 通过静电络合法自组装制备出各向异性一维磁性纳米线结构。所制备纳 米线结构呈一维准直结构。纳米线结构受组装过程中温度、电荷比值等因素 影响。结果表明温度越高，所制备纳米线长度越长，温度越低，纳米线长度 较小；电荷比值Z=7时，所制备纳米线长度为18.62um，当Z=0.3时，纳米线 长度为75.97um，当正负电荷总数基本相等，即Z=1时，样品团聚较明显，未 形成明显一维结构。另外，本文还探讨了纳米线的组装机理，为纳米线组装 制备提供了新的方法。 关键 词： γ-Fe2O3 超顺 磁纳 米颗 粒 聚丙 烯酸 阳离 子聚 电解 质聚 合物 一 维纳米线结构 组装机理 Abstract The one-dimensional magnetic nanostructured wires have attracted more and more attentions due to its potential application in cell manipulation, microfluidics and micro-mechanics, Therefore, it is emerging to find a simple and effective methodology to sythesis wires and to study the corresponding assembly mechanism. In this study, we use the electrostatic complexation to synthesis the one-dimensional magnetic nanostructured wires. The structure of the wires were controlled by tunning the charge ratio Z between the γ-Fe2O3 nanoparticles and cationic polyelectrolyte polymer and the temperature T during the synthesis. Here, the γ-Fe2O3 nanoparticles made by co-precipitation were characterized by using XRD, VSM, TEM and DLS, indicating that the γ-Fe2O3 nanoparticles have a typical superparamagnetic properties, relatively uniform particle size, and a small polydispersity. The bare nanoparticles were coated by an anionic polymer in order to improve its colloidal stability and further fonctionality. DLS study shows that the organic coating thickness is about 5 nm. The coated nanoparticles was found to have remarkable colloid stability in aqueous with high concentration of salt and complicated bioligical enviro