基于超分子化学作用的PVDF膜改性及其在处理低浓度含油废水中的应用研究-环境工程专业论文.docxVIP

南京理工大学博士论文 南京理工大学博士论文 基于超分子化学作用的PVDF膜改件及蒜存处珲低浓度含油废水中的应用研究 ABSTRACT In this dissertation,a research has been made on the surface hydrophilic modification of porous polyvinylidene fluoride(PVDF)m锄brane based on supramolecular chemistry process and its application in the treatment oflow concentration oily wastewater． First,the mechanism of surface hydrophilic modification of PVDF membrane based on supramolecular chemistry process has been presented．Supramolecular chemistry is the chemistry ofordered arrays ofmolecular units based on non-covalent weak interactions；it maiuly studies the structure and function of the molecular assembly which are formed through the non-covalent bond weak interaction between two or among more molecules, such嬲hydrogen bond,van der waais force．dipole／dipole interaction, hydrophilic／hydrophobie interaction and their synergistic reaction．As a branch of supramolecular chemistry,the construction and function ofthe layer assembly ofultrathin membrane has been the hot issue to be studied．There ale many kinds of impetuses to prepare ultrathin film by alternant sediment technique，such as electrostatic force， hydrogen bond,coordination bond,charge transfer,vall dcr waals force．矗讯interaction, molecular recognition or the synergistic reaction of several forces above．Though those all arc weak interaction forces and the intensity is not strong，the total force is strong enough to preserve the stability ofassembly system ffthese weak interactions arc accumulated． Taking the water contact angel and pure water flux as the performance indexes,the main influence factors on performance ofmodifled membrane arc researched,and the main experimental conditions ofmemb砌e modification are determined．After modification,the water contact angle is 35。and pure water flux are over 100Lm2h1，which are improved greatly compared to the PVDF membrane,and the oil rejec-tion ratio is increased dramatically．Moreover,the thermal stability and the mechanical stability of modified m锄