甲烷液相部分氧化合成甲醇过程研究-高校化学工程学报.PDF

19 1 No.1 Vol.19 2005 2 Journal of Chemical Engineering of Chinese Universities Feb. 2005 1003-9015(2005)01-0054-05 1,2 1 2 2 , , , (1. , 710049; 2. , 710069) SO I 3 2 0.099 mol⋅L−1473K(SO 50%(wt))3h82.65%, 3 70.43% , SO3 TQ031.7 TQ223.121 A Study of Catalysis Oxidation of Methane to Methanol in Liquid Phase CHEN Li-yu1, 2 1 2 2 , YANG Bo-lun , ZHANG Xiu-cheng , DONG Wu (1. Department of Chemical Engineering, Xi’an Jiaotong University, Xi’an 710049, China; 2. School of Chemical Engineering, Northwest University, Xi’an 710069, China) Abstract: The selective oxidation of methane in oleum was catalyzed by the iodine compounds. The effect of the catalysts kinds, catalyst concentration, reaction temperature and the amount of SO3 in oleum on the conversion of methane and the yield of methanol were investigated. The mechanism of reaction in oluent was studied and the functions of oluent were also discussed. Among the tested catalysts, I2 showed the highest activity and selectivity. Under the optimal reaction condition, that is, the concentration of I2 is 0.099mol⋅L−1, reaction temperature is 473 K, pressure of methane is 3.4MPa, reaction time is for 3h, the content of sulfur trioxide in oleum is about 50%, the 82.65% conversion of methane and the 70.43% yield of methanol could be obtained. The mechanism analysis shows that methane is transformed into methyl bisulfate firs