阳离子红染料的臭氧氧化动力学研究-高校化学工程学报.PDF

19 1 No.1 Vol.19 2005 2 Journal of Chemical Engineering of Chinese Universities Feb. 2005 : 1003-9015(2005)01-0108-05 , , (, 310027) pHX-GRL X-GRL pH k 77505exp(=−18062 / RT )[OH− ]0.003 (L⋅mol− 1⋅s− 1) 18.062kJ⋅mol− 1 X-GRL X703.1 X791 A Reaction Kinetics of Cationic Red X-GRL Ozonation ZHAO Wei-rong, SHI Hui-xiang, WANG Da-hui (Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China) Abstract : The reaction between ozone and aqueous solution of Cationic Red X-GRL was investigated by gas absorption experiments in a semi-batch reactor. The experiments were conducted by modifying the gas flow rate, initial dye concentration, temperature and pH. The liquid mass transfer coefficient, the interfacial area and the stoichiometric ratio between ozone and dye were evaluated. A model based on the film theory was used to determine the rate constant and the kinetic regime. The Hatta number of the reaction is between 0.026 and 0.041, which indicates that the reaction occurs in the liquid bulk, corresponding to the slow kinetic regime. The kinetics results obtained support a second order overall reaction, first order with respect to both reactions of ozone and dye. The rate constant was correlated as a function of temperature and pH with activation energy of 18.062 kJ·mol− 1 by the expression: − 0.003 − 1 − 1 k 77505exp(=−18062 / RT )[OH ] (L·mol ·s ). Key words: Cationic Red X-GRL; ozonation; reaction kinetics; mass transfer 1 ~[1] [2] X-