TXIB对Mextral973H从铜氨溶液中萃取铜及氨的影响研究.docVIP

doi：10.3969/j.issn.1007-7545.2019. doi：10.3969/j.issn.1007-7545.2019.03.002 李鹏程1,2，王晓鸽3，张文娟3 (1.东北大学 冶金学院，沈阳 110819；2.智奇铁路设备有限公司，太原 030032；3.北京科技大学，北京 100083) 摘要：以Cu-NH3-NH4Cl-H2O体系为研究对象，TXIB（2,2,4-三甲基-1,3-戊二醇双异丁酸酯）为改质剂，考察TXIB用量、萃取剂浓度、萃取相比、水相铜浓度、氨浓度等对萃取剂Mextral973H从铜氨溶液中萃取铜及氨的影响。结果表明，TXIB的使用可以显著降低氨的共萃而不影响铜的萃取。在萃取相比O/A=1/1、有机相浓度20%、铜浓度18.0 g/L、氨浓度84.0 g/L的条件下，向有机相中添加10%的TXIB后，铜萃取率由60.44%变化为60.20%，有机相共萃氨量从410.2 mg/L降至154.8 mg/L。 关键词：氨性溶液；羟肟类萃取剂；共萃氨；TXIB；Mextral973H 中图分类号：TF811 文献标志码：A 文章编号：1007-7545（2019）03-0000-00 Effect of TXIB on Extraction of Copper and Ammonia from Ammoniacal Solution by Mextral973H LI Peng-cheng1,2, WANG Xiao-ge3, ZHANG Wen-juan3 (1. School of Metallurgy, Northeastern University, Shenyang 110819, China; 2. Zhiqi Railway Equipment Co. Ltd., Taiyuan 030032, China; 3. University of Science and Technology Beijing, Beijing 100083, China) Abstract：With TXIB (2,2,4-trimethyl-1,3-pentanediol diisobutyrate) as modifier and Mextral973H as extractant, effects of TXIB dosage (volume fraction), extractant concentration (volume fraction), O/A ratio, Cu2+ and ammonia concentration in feed solution on extraction of copper and ammonia in Cu-NH3-NH4Cl-H2O system were investigated. The results show that addition of TXIB in organic can reduce extraction of ammonia remarkably, and has little effect on copper extraction. Copper extraction rate is 60.44% and ammonia in loaded organic is 410.2 mg/L under the conditions including O/A=1/1, Metral973H concentration of 20%, copper concentration of 18.0 g/L, and ammonia concentration of 84.0g/L in feed solution. Copper extraction rate is 60.20% and ammonia in loaded organic is 154.8 mg/L extracted by 20% Metral973H with addition of 10% TXIB. Key words：ammoniacal solution; hydroxyoxime extractant; ammonia extraction; TXIB; Mextral973H 目前，我国铜矿床普遍呈现贫矿多、富矿少、伴生矿多、单一矿少、矿石品位偏低等特点，其矿石的平均品位仅为0.50%，难选冶矿及低品位矿约占全国铜矿储量的三分一[1-2]。湿法炼铜由于对低品位矿具有适应性强、投资成本低、环境友好等特点，近年来得到了迅速发展[3]。针对碱性脉石含量高而氧化铜品位偏低的铜矿，氨浸法无疑是最经济有效的方法。通过向矿石中添加氨—氯化铵（硫酸铵、碳酸铵等）缓冲体