尖晶石型铁氧体的合成及多铁性研究-化学工艺专业论文.docxVIP

对其形貌、结构、磁性、铁电和介电性能等方面进行了测试，讨论了它 在室温下的多铁性能。 关键词：多铁性材料；ZnFe2O4；Cd/Pb/Al 掺杂; 磁性；铁电性 ABSTRACT The term multiferroism has been coined to describe materials in which two or all three of ferroelectricity, ferromagnetism and ferroelasticity occur in the same phase. The ferrite plays an important part in the study of multiferroics as a kind of important matrix. It has a potential applications in high density data storage, magnetic, magnetic resonance imaging (such as contrast agents) and magnetic refrigerants. Spinel zinc ferrites were widely used in military and electronic field for its good dielectric performance, high frequency characteristics, high resistivity, small loss and so on. In this article, single-phase spinel-type ZnFe2O4, CdxZn1-xFe2O4, PbxZn1-xFe2O4 and ZnAlxFe2-xO4 were prepared by solvothermal method. The structures, morphologies, magnetism and ferroelectricity of them were investigated by X-ray diffraction (XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), vibrating sample magnetometer (VSM) and ferroelectric analyzer respectively.The main results and conclusions are as follows: A novel method of synthesizing multiferroic spinel ferrites was proposed. Using sodium acetate, iron salt and zinc salt as reactants, ZnFe2O4 spinel ferrite was synthesized by a HYPERLINK /dict_result.aspx?searchword=%e6%ba%b6%e5%89%82%e7%83%ad%e6%b3%95amp;tjType=sentenceamp;styleamp;t=solvent-thermal%2Bmethod solvothermal method. The structure, surface morphology, magnetism and ferroelectricity of it were investigated by XRD，SEM，TEM,VSM and ferroelectric analyzer respectively and its multiferroic property at room temperature was discussed. A novel method of synthesizing spinel ferrites doped by element was proposed. Using sodium acetate, iron salt, zinc salt and cadmium salt as reactants, CdxZn1-xFe2O4 spinel ferrites were synthesized by a HYPERLINK /dict_result.aspx?searchword=%e6%ba%b6%e5%89%82%e7%83%ad%e6%b3%95amp;tjType=sentenceamp;style