以酸性溶出法自电弧炉集尘灰中回收锌.DOC

以酸性溶出法自電弧爐集塵灰中回收鋅 Recovery of Zinc from Electric Arc Furnace Flue Dust by Acidic Leaching 研究生：施諦捷 Shih,Ti-Chieh 指導教授：張國慶 Chang, Kuo-Ching 【摘要】 本研究之目的為自電弧爐煉鋼集塵灰中回收其有價之金屬鋅。以酸性溶出方法來回收鋅，最主要可避免戴奧辛排放的風險。利用氯化銨搭配硫酸的兩段式溶出，使用電析的方法來回收鋅粉末。電析前溶出液的除雜質方法為鋅粉置換與控制pH來除鐵，目的在純化鋅。分別以不同固液比、溫度、時間、及浸出液濃度作變因探討，觀察電析率與金屬回收率。第一階段溶出之最佳條件為100% 飽和氯化銨溶液，固液比1:10、溫度40℃、30分鐘，由實驗結果得知鋅溶出率為37.00%，電析率97.80%，鋅粉純度85.46%，而回收率達到36.17%。第二階段溶出之最佳條件為9N硫酸，固液比1:9、溫度50℃、60分鐘，結果得知鋅溶出率達到59.83%，電析率98.95%，鋅粉純度91.03%，而回收率達到45.60%。控制硫酸溶出液pH所產生的氫氧化鐵膠羽狀沉澱物會使鋅離子產生共沉造成鋅離子損失，故以稀釋溶出液方式來減小鋅損失量。硫酸溶出液稀釋倍數為4倍且以氨水控制pH至8，可使氫氧化鐵沉澱物吸附鋅離子比例降至22.98%，鐵去除率達到99.9%。鋅粉除雜質之最適量為需置換金屬重量之1.5~2.5倍。實驗結果鋅總溶出率為96.83%，平均電析率為98.38%，鋅總回收率達到81.78%，鋅粉平均純度為88.25%。 關鍵字：電弧爐集塵灰、回收、電析 【Abstract】 The aim of this study was to recover valuable zinc metal fro electric arc furnace flue dust. Concerning the possibility of dioxin discharge, acidic leaching process was chosen, instead of high temperature pyro-metallurgical process, to recover zinc. Two step leaching processes utilized ammonium chloride and sulfuric acid respectively with subsequent electrolysis to obtain zinc powder were performed in this study. To remove impurity, zinc powder was added into leached liquid and pH value was adjusted to displace and precipitate iron ion in solution. In first stage, leaching by 100% saturation solution of NH4Cl at 40℃ for 30 minutes with a solid/liquid ratio of 1/10 obtained the best result. The recovery efficiency of 36.17% was achieved in this stage where 37 % of zinc was leached, 97.8% of zinc was electrolyzed, and zinc powder with 85.46 % purity was obtained. In second stage, leaching by 9N H2SO4 at 50℃ for 1 hour with a solid/liquid ratio of 1/9 obtained the best result. The recovery efficiency of 45.60% was achieved in this stage where 59.83% of zinc was leached, 98.95% of zinc was electrolyzed, and zinc powder with 91.03 % purity was obtained. To minimize the chemical co-precipitation effects, which would reduce the quantity of recovered zinc, d