间歇萃取精馏分离环己烷—四氢呋喃的研究-制药工程专业论文.docxVIP

中文摘要环己烷(CH)、四氢呋喃(THF)是重要的有机合成助剂，在涂料、胶粘剂等 中文摘要 环己烷(CH)、四氢呋喃(THF)是重要的有机合成助剂，在涂料、胶粘剂等 领域广泛使用。但由于环己烷和四氢呋喃的相对挥发度较小，应用普通精馏方法 难以对其进行有效的分离，因此本文进行了以N，N．二甲基甲酰胺(DMF)为萃 取剂的间歇萃取精馏的实验研究。 本文首先采用数学计算与汽液平衡釜实验相结合的方法确定环己烷一四氢 呋喃汽液平衡关系，然后利用基团贡献法选择该二元物系萃取精馏的萃取剂并通 过气液平衡实验进行萃取剂效果的验证以及适宜的萃取剂溶剂比，实验结果表 明，所选溶剂N，N一二甲基甲酰胺可以增大环己烷一四氢呋喃的相对挥发度，当 萃取剂溶剂比为1：1时的分离效果较好。 在实验室小试条件下进行了间歇萃取精馏分离环己烷一四氢呋喃的精馏实 验，分别比较了多个不同浓度混合物原料样的萃取剂用量和萃取精馏的难易程 度，并且进一步比较不同萃取剂加入速率下的萃取精馏效果问题，实验结果表明 溶剂比l：l时的溶剂流率为适宜的溶剂加入速率。 本文还针对该间歇萃取精馏过程进行模拟计算，建立了描述间歇萃取精馏 过程的平衡级恒摩尔持液模型，采用两点隐含法对数学模型进行求解，通过 Fortran90语言编制程序，结果表明此计算方法的稳定性和收敛性较好，与实验 数据比较吻合，从而说明模型的可靠性。 关键词：间歇萃取精馏萃取剂环己烷四氢呋喃模拟 ABSTRACTCyclohexane ABSTRACT Cyclohexane and THF abe very important intermediate in organic synthesis．They abe widely used in covering material，adhesive and so Oil．But cyclohexane and THF having the small relative volatility Can not be separated by conventional distillation． So this paper discusses the batch extractive distillation using DMF as the extractive solvent to separate the mixture． Firstly,the vapor-liquid equilibrium curve of THF·cyclohexane was determined by combination of calculation and experimented data．Then select the extractive solvent of the binary mixture using group contribution method and validate the effect of the solvent though the vapor-liquid equilibrium experiment．The feasible solvent ratio is also determined．The results of experiment showed that DMF call augment the relative volatility,the solvent ratio which is 1：1 is the feasible solvent ratio． Secondly,the small scale batch extractive distillation was done to separate the binary mixture．In these experiments，the solvent consumption and the separate degree of the extractive distillation were compared during the different concentration l aW material．The effect of the operation parameter solvent flow late Was studied．The result ofthe experiment showed that the feasible solvent ratio is 1：1． Thirdly,this paper calculated this batch extractive distillation process，and the equilibrium mode des